Synthesis and characterization of two-photon chromophores based on a tetrasubstituted tetraethynylethylene scaffold

Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/101048

Title:	Synthesis and characterization of two-photon chromophores based on a tetrasubstituted tetraethynylethylene scaffold
Authors:	林子超;Lin, Tzu-Chau;Liu, Yi-You;Li, May-Hui;Liu, Che-Yu;Tseng, Sheng-Yang;Wang, Yu-Ting;Tseng, Ya-Hsin;Chu, Hui-Hsin;Luo, Chih-Wei
Contributors:	理學院化學學系
Keywords:	absorption;Absorption, Physicochemical;Chemistry;chromophores;Dyes;Enediynes - chemistry;Fluorescent Dyes - chemical synthesis;Fluorescent Dyes - chemistry;heterocycles;Molecular Structure;nonlinear optics;Photons;Pyridazines - chemistry;Pyridines - chemistry;Quinoxalines - chemistry;Sonogashira reaction;Spectrometry, Fluorescence
Date:	2014-01-01
Issue Date:	2026-04-21 14:22:08 (UTC+8)
Publisher:	John Wiley and Sons Ltd;Weinheim: WILEY-VCH Verlag
Abstract:	摘要： A new series of model dye molecules composed of three multibranched analogues based on the tetrasubstituted tetraethynylethylene structural motif have been synthesized and experimentally shown to possess strong and widely dispersed two‐photon absorption (2PA) in the near‐IR region. It was found that the spectral position of the major 2PA band could be tuned by the electronic nature of the selected substitution units. The studied model fluorophores also exhibited fairly low photodegradation of their fluorescence intensity even under prolonged UV‐light irradiation, which is beneficial for the development of fluorescence probes that are needed for long‐term light exposure. Furthermore, representative chromophores were selected to demonstrate the power‐control properties within the femtosecond and nanosecond time domains. Two is better than one: Multibranched chromophores based on the tetrasubstituted ethynylethylene skeleton with functionalized quinoxalinoids as aryl substituents are synthesized and shown to possess strong and widely dispersed two‐photon absorption in the near‐IR region. This molecular archetype is also demonstrated to possess optical power‐limiting properties and optical power‐stabilization properties toward laser pulses in various time domains. 其他題名： Chem. Asian J 出版者： Weinheim: WILEY-VCH Verlag 出版日期： 2014-06 出處： Chemistry, an Asian journal, 2014-06, Vol.9 (6), p.1601-1610 版權： 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim 版權： 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. 版權： 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 識別號： ISSN: 1861-4728 識別號： ISSN: 1861-471X 識別號： EISSN: 1861-471X 識別號： DOI: 10.1002/asia.201402094 識別號： PMID: 24771487
Appears in Collections:	[Department of Chemistry] journal & Dissertation

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