New nanostructured zinc phosphite templated by cetyltrimethylammonium cations: Synthesis, crystal structure, adsorption, and photoluminescence properties

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題名:	New nanostructured zinc phosphite templated by cetyltrimethylammonium cations: Synthesis, crystal structure, adsorption, and photoluminescence properties
作者:	李光華;Wang, Chih-Min;Chang, Tsung-Yuan;Chiu, Cheng-Wei;Lin, Hsiu-Mei;Lii, Kwang-Hwa
貢獻者:	理學院化學學系
日期:	2014-04-07
上傳時間:	2026-04-21 14:25:24 (UTC+8)
出版者:	American Chemical Society;United States: American Chemical Society
摘要:	摘要： Nanostructured zinc phosphite templated by cetyltrimethylammonium (CTA+) cations was synthesized using a hydro(solvo)thermal method. This is the first example of a crystalline metal phosphite containing long carbon tails of the CTA+ ions as templates in its structure, as is structurally characterized by single-crystal X-ray diffraction. The 2D inorganic structures with 4.82 topologies are constructed from the interconnection of tetrahedral ZnO3Br and HPO3 units, which are sandwiched between CTA+ ion surfactants in a packing behavior of a largely lamellar liquid-crystalline structure to extend the interlayer d spacing to 28.05 Å. Adsorption experiment shows selective adsorption properties of 1-naphthol and a adsorption capacity of 0.17 mmol/mmol (CTA)ZnBr(HPO3). This compound has potential as an adsorbent for the removal of 1-naphthol pollutant from wastewater. In addition, the naphthol-adsorbed sample shows interesting luminescent properties that are different from that of an as-synthesized sample. The crystal structure, thermal stability, IR spectrum, adsorption, and photoluminescence properties have been studied. 其他題名： Inorg. Chem 出版者： United States: American Chemical Society 出版日期： 2014-04-07 出處： Inorganic chemistry, 2014-04, Vol.53 (7), p.3266-3268 資源來源： American Chemical Society Journals 版權： Copyright © 2014 American Chemical Society 識別號： ISSN: 0020-1669 識別號： ISSN: 1520-510X 識別號： EISSN: 1520-510X 識別號： DOI: 10.1021/ic500068x 識別號： PMID: 24661090
顯示於類別:	[化學學系] 期刊論文

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