Structural characteristics and non-linear optical behaviour of a 2-Hydroxynicotinate-containing zinc-based metal-organic framework

Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/101433

Title:	Structural characteristics and non-linear optical behaviour of a 2-Hydroxynicotinate-containing zinc-based metal-organic framework
Authors:	張伯琛;Mendiratta, Shruti;Lee, Cheng-Hua;Lee, Sih-Ying;Kao, Ya-Chuan;Chang, Bor-Chen;Lo, Yih-Hsing;Lu, Kuang-Lieh
Contributors:	理學院化學學系
Keywords:	2-hydroxynicotinic acid;4,4′-bipyridine;Chemistry;Coordination Complexes - chemical synthesis;Coordination Complexes - chemistry;Crystallography, X-Ray;emission;Ligands;metal-organic framework;Models, Molecular;Nicotinic Acids - chemical synthesis;Nicotinic Acids - chemistry;non-linear optics;Nonlinear Dynamics;Optical Phenomena;Optics;Pyridines - chemistry;Spectroscopy, Fourier Transform Infrared;Zinc - chemistry
Date:	2015-01-01
Issue Date:	2026-04-21 14:33:50 (UTC+8)
Publisher:	MDPI Multidisciplinary Digital Publishing Institute;Switzerland: MDPI AG
Abstract:	摘要： Materials with non-linear optical (NLO) properties play an important role in the construction of electronic devices for optical communications, optical data processing and data storage. With this aim in mind, a Zn(II)-based metal-organic framework [Zn2(nica)2(bpy)1.5(H2O)]×0.5(bpy)×3H2On (1), was synthesized using 4,4ʹ-bipyridine (bpy) and a potentially bidentate ligand, 2-hydroxynicotinic acid (H2nica) with a salicylate binding moiety. A single-crystal X-ray diffraction analysis revealed that compound 1 crystallized in the orthorhombic space group Fdd2 and was composed of a three dimensional porous framework. Since Fdd2 belonged to a class of non-centrosymmetric space groups, we therefore investigated the non-linear optical behaviour of compound 1. Photoluminescence studies revealed that compound 1 exhibited a blue light emission with a maxima at 457 nm. 其他題名： Molecules 出版者： Switzerland: MDPI AG 出版日期： 2015-05-18 出處： Molecules, 2015-05, Vol.20 (5), p.8941-8951 資源來源： Publicly Available Content Database 版權： Copyright MDPI AG 2015 版權： 2015 by the authors. 2015 識別號： ISSN: 1420-3049 識別號： ISSN: 1433-1373 識別號： EISSN: 1420-3049 識別號： EISSN: 1433-1373 識別號： DOI: 10.3390/molecules20058941 識別號： PMID: 25993422
Appears in Collections:	[Department of Chemistry] journal & Dissertation

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