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    Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/101457


    Title: Template-free synthesis of nanoporous gadolinium phosphonate as a magnetic resonance imaging (MRI) agent
    Authors: 謝發坤;Pramanik, Malay;Shieh, Fa-Kuen;Alshehri, Saad M;Alothman, Zeid Abdullah;Wu, Kevin C.-W;Yamauchi, Yusuke
    Contributors: 理學院化學學系
    Date: 2015-01-01
    Issue Date: 2026-04-21 14:34:21 (UTC+8)
    Publisher: Royal Society of Chemistry
    Abstract: 摘要: A new series of organic-inorganic hybrid porous gadolinium phosphonate (GdP) materials have been synthesized using benzene-1,3,5-triphosphonic acid as a phosphonic acid linker through a simple hydrothermal technique. The particle size and morphology are well controlled through the selection of suitable reaction conditions. The obtained materials exhibit very high specific surface area and crystalline pore walls with a triclinic structure having unit cell parameters a = 7.76 (3) Å; b = 8.60 (6) Å; c = 14.09 (7) Å; α = 100.08 (4)°; β = 84.23 (6)°; γ = 116.29 (6)°. The obtained GdP materials are further used as a magnetic resonance imaging (MRI) contrast agent with r 1 and r 2 values of 2.6 and 4.7 s −1 mM −1 , respectively. Organic-inorganic hybrid porous gadolinium phosphonate materials are synthesized using benzene-1,3,5-triphosphonic acid as phosphonic acid linker.
    出版日期: 2015-05-12
    資源來源: Royal Society of Chemistry
    識別號: EISSN: 2046-2069
    識別號: DOI: 10.1039/c5ra02004b
    Appears in Collections:[Department of Chemistry] journal & Dissertation

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