摘要： An organic–inorganic hybrid zinc phosphate with 28‐ring channels was synthesized by use of an organic ligand instead of organic amine template under a hydro(solvo)thermal condition. This crystalline zinc phosphate contains large channels constructed from 28 zinc and phosphate tetrahedral units. The walls of the channels consist of two types of zincophosphate chains, in which the Zn atoms are coordinated by 2,4,5‐tri(4‐pyridyl)‐imidazole ligands as pendent groups. This compound exhibits yellow emission and interesting properties of removing cobalt, cadmium, and mercury cations from aqueous solution. A new two‐dimensional organic–inorganic hybrid zincophosphate was also obtained by changing the solvent mixture ratios in the synthesis. Zincophosphate chains: An organic–inorganic hybrid zinc phosphate with 28‐ring channels was synthesized. This study provides a new route to the synthesis of inorganic frameworks with large channels through the use of organic ligands instead of organic amines. Its photoluminescence and the properties of removal of metal cations from aqueous solutions have also been studied (see figure). 其他題名： Chem. Eur. J 出版者： Weinheim: WILEY-VCH Verlag 出版日期： 2015-01-26 出處： Chemistry : a European journal, 2015-01, Vol.21 (5), p.1878-1881 資源來源： Alma/SFX Local Collection 版權： 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim 版權： 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. 版權： 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim 識別號： ISSN: 0947-6539 識別號： ISSN: 1521-3765 識別號： EISSN: 1521-3765 識別號： DOI: 10.1002/chem.201405676 識別號： PMID: 25469917 識別號： CODEN: CEUJED
