Unraveling simultaneously enhanced open-circuit voltage and short-circuit current density in P3HT:ICBA:2,3-pyridinediol blended film based photovoltaics

Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/101503

Title:	Unraveling simultaneously enhanced open-circuit voltage and short-circuit current density in P3HT:ICBA:2,3-pyridinediol blended film based photovoltaics
Authors:	江建宏;Chang, Sheng Hsiung;Chiang, Chien-Hung;Tseng, Zong-Liang;Chiu, Kuo-Yuan;Tai, Chao-Yi;Wu, Chun-Guey
Contributors:	理學院化學學系
Keywords:	Balancing;Blended;Current density;Electric potential;energy transfer;exciton;Excitons;photovoltaic;Photovoltaic cells;Solar cells;Voltage
Date:	2015-05-20
Issue Date:	2026-04-21 14:36:28 (UTC+8)
Publisher:	IOP Publishing Ltd.;IOP Publishing
Abstract:	摘要： A comprehensive study was carried out to understand the simultaneous enhancement of the open-circuit voltage and short-circuit current density in P3HT:ICBA:2,3-pyridinediol blended film based photovoltaics. Femtosecond time-resolved photoluminescence, steady-state absorption spectrum, atomic force microscopy and 2D grazing-incidence wide-angle x-ray scattering were used to explore the transport characteristics of excitons. The comparatively faster exciton dissociation in the P3HT:ICBA:2,3-pyridinediol blended film is attributed to the higher mobility of the excitons in P3HT. The space-charge limited-current measurements show the carrier mobility to be more balanced in the P3HT:ICBA:2,3-pyridinediol blended film than in the P3HT:PCBM:2,3-pyridinediol blended film, which is beneficial to the photo-induced current extraction. The enhanced short-circuit current density originates from the higher exciton dissociation yield in combination with the more balanced electron-hole mobility. The results should aid the design of an organic film for high-efficiency photovoltaics. 其他題名： JPhysD 其他題名： J. Phys. D: Appl. Phys 出版者： IOP Publishing 出版日期： 2015-05-20 出處： Journal of physics. D, Applied physics, 2015-05, Vol.48 (19), p.195104-5 資源來源： Institute of Physics Journals 版權： 2015 IOP Publishing Ltd 識別號： ISSN: 0022-3727 識別號： EISSN: 1361-6463 識別號： DOI: 10.1088/0022-3727/48/19/195104 識別號： CODEN: JPAPBE
Appears in Collections:	[Department of Chemistry] journal & Dissertation

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