Synthesis and two-photon absorption properties of truxene-cored chromophores with functionalized pyrazine units fused as the end-groups

Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/101603

Title:	Synthesis and two-photon absorption properties of truxene-cored chromophores with functionalized pyrazine units fused as the end-groups
Authors:	林子超;Lin, Tzu-Chau;Tsai, Bo-Kai;Huang, Tzu-Yu;Chien, Wei;Liu, Yi-You;Li, May-Hui;Tsai, Ming-Yu
Contributors:	理學院化學學系
Keywords:	Fluorene;Optical power-limiting and stabilization;Pyrazine;Truxene;Two-photon absorption;Two-photon-indeuced fluorescence
Date:	2015-09-01
Issue Date:	2026-04-21 14:38:51 (UTC+8)
Publisher:	Elsevier BV;Elsevier Ltd
Abstract:	摘要： A new set of model chromophores derived from a truxene core fused with varied number and size of functionalized pyrazine units was designed and synthesized for the tentative exploration of possible connections between the molecular structure and their linear/nonlinear optical properties. The initial experimental results have indicated that these model compounds not only possess strong and widely dispersed two-photon absorption (2 PA) within the near-IR region but also show the ascending overall 2 PA when the molecular structure varies with increase in complexity and molecular weight, which implies that both the number of branches and the size of π-framework are important factors to the molecular 2 PA in this model chromophore system. On the other hand, the studied model chromophores also manifest very good photostability within their two-photon active spectral region even under a prolonged irradiation of IR laser pulses. In addition, a representative chromophore is selected to demonstrate optical power-limiting and power-stabilization performance against nanosecond laser pulses. [Display omitted] •A series of multi-polar chromophores based on the structural motif of pyrazine-fused truxene has been synthesized.•These model fluorophores manifest strong and wide dispersed two-photon absorption in the near infrared region.•Optical-power-limiting/stabilization behavior of a representative dye molecule is demonstrated. 出版者： Elsevier Ltd 出版日期： 2015-09-01 出處： Dyes and pigments, 2015-09, Vol.120, p.99-111 版權： 2015 Elsevier Ltd 識別號： ISSN: 0143-7208 識別號： EISSN: 1873-3743 識別號： DOI: 10.1016/j.dyepig.2015.04.008
Appears in Collections:	[Department of Chemistry] journal & Dissertation

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