π-Conjugated bis(terpyridine)metal complex molecular wires

Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/101644

Title:	π-Conjugated bis(terpyridine)metal complex molecular wires
Authors:	吳國暉;Sakamoto, Ryota;Wu, Kuo-Hui;Matsuoka, Ryota;Maeda, Hiroaki;Nishihara, Hiroshi
Contributors:	理學院化學學系
Keywords:	Coordination compounds;Customizing;Electrodes;electron transfer;Electron transport;Electronics;Ligands;Resultants;Wire
Date:	2015-11-07
Issue Date:	2026-04-21 14:39:56 (UTC+8)
Publisher:	Royal Society of Chemistry;England
Abstract:	摘要： Bottom-up approaches have gained significant attention recently for the creation of nano-sized, ordered functional structures and materials. Stepwise coordination techniques, in which ligand molecules and metal sources are reacted alternatively, offer several advantages. Coordination bonds are stable, reversible, and self-assembling, and the resultant metal complex motifs may contain functionalities unique to their own characteristics. This review focuses on metal complex wire systems, specifically the bottom-up fabrication of linear and branched bis(terpyridine)metal complex wires on electrode surfaces. This system possesses distinct and characteristic electronic functionalities, intra-wire redox conduction and excellent long-range electron transport ability. This series of comprehensive studies exploited the customizability of bis(terpyridine)metal complex wires, including examining the influence of building blocks. In addition, simple yet effective electron transfer models were established for redox conduction and long-range electron transport. A fabrication technique for an ultra-long bis(terpyridine)metal complex wire is also described, along with its properties and functionalities. This review focuses on the bottom-up fabrication of linear and branched bis(terpyridine)metal complex wires on electrode surfaces, which feature distinct and characteristic electronic functionalities such as intra-wire redox conduction and excellent long-range electron transport ability. 其他題名： Chem Soc Rev 出版者： England 出版日期： 2015-11-07 出處： Chemical Society reviews, 2015-11, Vol.44 (21), p.7698-7714 資源來源： Royal Society of Chemistry 識別號： ISSN: 0306-0012 識別號： ISSN: 1460-4744 識別號： EISSN: 1460-4744 識別號： DOI: 10.1039/c5cs00081e 識別號： PMID: 25864838
Appears in Collections:	[Department of Chemistry] journal & Dissertation

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