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    NCU Institutional Repository > 理學院 > 化學學系 > 期刊論文 >  Item 987654321/101678


    請使用永久網址來引用或連結此文件: https://ir.lib.ncu.edu.tw/handle/987654321/101678


    題名: Controlling the morphology of poly(3-hexylthiophene)/methanofullerene film through a dynamic-cooling and freeze-drying process
    作者: 陳錦地;Huang, Ping-Tsung;Chou, Cheng-Wei;Lin, Bo-Yu;Shi, Zhong-En;Huang, Yu-Jui;Chen, Chin-Ti;Cheng, Chao-Han;Wang, Juen-Kai
    貢獻者: 理學院化學學系
    關鍵詞: Agglomerates;Agglomeration;Aggregates;Current density;Devices;dynamic cooling;Esters;freeze drying;Illumination;morphology;P3HT;PCBM;Solvents
    日期: 2016-01-01
    上傳時間: 2026-04-21 14:40:39 (UTC+8)
    出版者: John Wiley and Sons Ltd;Chichester, UK: John Wiley & Sons, Ltd
    摘要: 摘要: A dynamic‐cooling and freeze‐drying (DCFD) process has been applied to the fabrication of polymer solar cells. The dynamic‐cooling process allows poly(3‐hexylthiophene) molecules to aggregate in solution into a more organized structure during the cooling process; the freeze‐drying process prevents severe agglomeration of [6,6]‐phenyl‐C61‐butyric acid methyl ester (PCBM) during the solvent removing process. Application of these two processes to the preparation of the poly(3‐hexylthiophene)/methanofullerene photoactive layer results in an enhanced poly(3‐hexylthiophene) aggregation and smaller PCBM agglomerates. Devices fabricated using the DCFD process generate 14% more in current density than those prepared by the spin‐coating process under AM1.5G illumination. © 2015 Society of Chemical Industry A dynamic‐cooling and freeze‐drying (DCFD) process enhances aggregation of P3HT and prevents PCBM from severe aggregation. Current density of the devices fabricated by DCFD process increase by 14%.
    其他題名: Polym. Int
    出版者: Chichester, UK: John Wiley & Sons, Ltd
    出版日期: 2016-01
    出處: Polymer international, 2016-01, Vol.65 (1), p.66-71
    版權: 2015 Society of Chemical Industry
    版權: 2016 Society of Chemical Industry
    識別號: ISSN: 0959-8103
    識別號: EISSN: 1097-0126
    識別號: DOI: 10.1002/pi.5028
    識別號: CODEN: PLYIEI
    顯示於類別:[化學學系] 期刊論文

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