Enantioselective synthesis of (+)-brevipolide H

Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/101682

Title:	Enantioselective synthesis of (+)-brevipolide H
Authors:	侯敦仁;Chen, Ching-Nung;Hou, Duen-Ren
Contributors:	理學院化學學系
Date:	2016-01-01
Issue Date:	2026-04-21 14:40:44 (UTC+8)
Publisher:	Royal Society of Chemistry;England
Abstract:	摘要： The enantioselective synthesis of natural brevipolide H is reported for the first time. By way of Sharpless epoxidation of penta-1,4-dien-3-ol, both enantiomerically pure epoxides were converted to the corresponding olefins for cross metathesis. Subsequent transformations, including epoxide ring opening, esterifications, cyclopropanation, oxidation and ring-closing metathesis, provided the target molecule. This synthesis successfully addresses previous shortcomings in preparing brevipolides. The enantioselective synthesis of natural brevipolide H is reported for the first time. 其他題名： Org Biomol Chem 出版者： England 出版日期： 2016-07-12 出處： Organic & biomolecular chemistry, 2016-07, Vol.14 (28), p.6762-6768 資源來源： Royal Society of Chemistry 識別號： ISSN: 1477-0520 識別號： ISSN: 1477-0539 識別號： EISSN: 1477-0539 識別號： DOI: 10.1039/c6ob01071g 識別號： PMID: 27337141
Appears in Collections:	[Department of Chemistry] journal & Dissertation

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