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    Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/101835


    Title: Tuning polymer-surface chemistries and interfacial interactions with UV irradiated polystyrene chains to control domain orientations in thin films of PS-b-PMMA
    Authors: 孫亞賢;Sun, Ya-Sen;Wang, Ching-Tun;Liou, Jiun-You
    Contributors: 工學院化學工程與材料工程學系
    Keywords: Block copolymers;Irradiation;Orientation;Polystyrene resins;Quartz;Semiconductors;Thin films;Tuning
    Date: 2016-01-01
    Issue Date: 2026-04-21 14:47:21 (UTC+8)
    Publisher: Royal Society of Chemistry;England
    Abstract: 摘要: We demonstrate a simple, rapid, cost-effective and robust approach to modify the surface of a solid substrate, based on a UV-irradiated film of a general plastic polymer. Thin films of homopolymer polystyrene (PS) of controlled thickness were spin-coated on diverse metal, semiconductor and polymeric surfaces. Specific surface chemistry was tuned with UV irradiation in air (UVIA); interactions at the PS/substrate interface were enhanced with UV irradiation in nitrogen (UVIN). Oxidized and cross-linked PS served as a neutral surface on various metal, quartz, semiconductor and polymeric substrates to induce perpendicularly oriented cylinders or lamellae in a self-assembled block copolymer.
    其他題名: Soft Matter
    出版者: England
    出版日期: 2016-01-01
    出處: Soft matter, 2016-01, Vol.12 (11), p.2923-2931
    識別號: ISSN: 1744-683X
    識別號: ISSN: 1744-6848
    識別號: EISSN: 1744-6848
    識別號: DOI: 10.1039/C5SM02605A
    識別號: PMID: 26890311
    Appears in Collections:[Department of Chemical and Materials Engineering] journal & Dissertation

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