Preferential oxidation of CO in H2 stream on Au/CuO-CeO2 catalysts: Effects of calcination temperature

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Title:	Preferential oxidation of CO in H2 stream on Au/CuO-CeO2 catalysts: Effects of calcination temperature
Authors:	陳郁文;Chou, Ying-Chieh;Chen, Yu-Wen
Contributors:	工學院化學工程與材料工程學系
Keywords:	CALCINATION;Carbon monoxide;Catalysis;CATALYSTS;CERIUM ALLOYS (0 TO 50 CE);COPPER OXIDE;FUEL CELLS;Gold;Lattices;LATTICES (CRYSTAL);Oxygen;PARTICLE SIZE AND SHAPE;Streams;Transmission electron microscopy
Date:	2016-09-01
Issue Date:	2026-04-21 14:54:36 (UTC+8)
Publisher:	American Scientific Publishers
Abstract:	摘要： Nanoscaled gold particle supported on CuO-CeO sub(2) was used for preferential oxidation of carbon monoxide in hydrogen stream (PROX). CuO-CeO sub(2) support was prepared by co-precipitation method in order to incorporate more CuO into CeO sub(2) lattice. Gold was loaded on the support by deposition-precipitation method. These catalysts were characterized by N sub(2)-sorption, X-ray diffraction (XRD), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HR-TEM), and X-ray photoelectron spectroscopy (XPS). The PROX reaction was carried out in a fixed bed continuous flow reactor with a feed of CO:O sub(2):H sub(2):He = 1.33:1.33:65.33:32.01 in volume ratios. CO/O sub(2) molar ratio was fixed at 1 in the feed in order to magnify the difference between different catalysts. The particle size of gold was around 2-5 nm and Au particles were dispersed well on the support. CuO was incorporated into the lattice structure of CeO sub(2), resulting in increasing the lattice oxygen vacancy. The excess CuO would be on the surface of CeO sub(2). The incorporation of copper ion into ceria lattice promoted the oxygen storage capacity of ceria support and enhanced the activity of catalyst. The higher calcination temperature for the support resulted in higher crystallinity of CeO sub(2), leading to the higher activity. The CO selectivity increased with increasing CuO content. However, overloading of CuO would retard the CO conversion and selectivity of oxygen reacting with CO. The results showed that the catalyst with optimum CuO content and high calcination temperature could reach 100% CO conversion in hydrogen stream at the PEM fuel cells operating temperature (80-100 degree C). 出版日期： 2016-09-01 出處： Journal of nanoscience and nanotechnology, 2016-09, Vol.16 (9), p.9104-9110 識別號： ISSN: 1533-4880 識別號： EISSN: 1533-4899 識別號： DOI: 10.1166/jnn.2016.12885
Appears in Collections:	[Department of Chemical and Materials Engineering] journal & Dissertation

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