Charge trap assisted high efficiency in new polymer-blend based light emitting diodes

Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/103147

Title:	Charge trap assisted high efficiency in new polymer-blend based light emitting diodes
Authors:	張瑞芬;Hassan, M.U.;Liu, Yee-Chen;Hasan, Kamran ul;Butt, H.;Chang, Jui-Fen;Friend, R.H.
Contributors:	理學院光電科學與工程學系
Keywords:	Light emitting diodes;Poly(para-phenylenevinylenes);Polyfluorenes;Polymer-blend diodes
Date:	2016-03-01
Issue Date:	2026-04-23 11:24:18 (UTC+8)
Publisher:	Elsevier BV;Elsevier Ltd
Abstract:	摘要： Polymer blend system, F81−xSYx, based on mixture of poly (9,9-dioctylfluorene) (F8) and a poly (para-phenylenevinylene) (PPV) copolymer, superyellow (SY), has been proven to be a high performance blend material in polymer light emitting diode (PLED). This blend system exhibits luminance (L) >104cdm−2, luminous efficiency (η) >21cdA−1 and low operating voltage (V) ~3–10V. The performance can be credited to the large difference (~0.6eV) between the highest occupied molecular orbital (HOMO) levels of F8 (~5.8eV) and SY (~5.2eV), where, SY molecules serve as hole-traps in the F8 host polymer and reduce their mobility. This dictates a balanced charge injection into the emissive layer and results in overall increase in the device performance. [Display omitted] •New polymer blend F81-xSYx used as emissive layer in PLEDs exhibit high efficiency.•Difference between HOMOs of F8 and SY is exploited to reduce the hole mobility.•SY molecules in F8 act as hole traps and dictate the overall transport properties.•High efficiency of F81-xSYx based PLEDs is due to the balanced charge transport. 出版者： Elsevier Ltd 出版日期： 2016-03 出處： Nano Energy, 2016-03, Vol.21, p.62-70 版權： 2015 Elsevier Ltd 識別號： ISSN: 2211-2855 識別號： DOI: 10.1016/j.nanoen.2015.12.023
Appears in Collections:	[Department of Optics and Photonics] journal & Dissertation

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