Bimetallic PtM (M=Pd, Ir) nanoparticle decorated multi-walled carbon nanotube enzyme-free, mediator-less amperometric sensor for H 2O 2

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Title:	Bimetallic PtM (M=Pd, Ir) nanoparticle decorated multi-walled carbon nanotube enzyme-free, mediator-less amperometric sensor for H 2O 2
Authors:	劉炯權;Chen, Kuan-Jung;Chandrasekara Pillai, K.;Rick, John;Pan, Chun-Jern;Wang, Shih-Han;Liu, Chung-Chiun;Hwang, Bing-Joe
Contributors:	工學院材料科學與工程研究所
Keywords:	Amperometric sensor;Biological and medical sciences;Biotechnology;Fundamental and applied biological sciences. Psychology;H2O2 estimation;Pt-based bimetallic nanoparticles (NPs);PtPd NPs-decorated multi walled carbon nanotube electrode
Date:	2012-03-15
Issue Date:	2026-04-23 11:29:11 (UTC+8)
Publisher:	Elsevier Ltd.;Kidlington: Elsevier B.V
Abstract:	摘要： ► PtPd and PtIr NPs-decorated multiwalled carbon nanotube nanocatalysts (PtM/MWCNTs) were prepared by a modified Watanabe method. ► PtPd/MWCNTs/GC electrode exhibited a low detection limit of 1.2μM. ► PtPd/MWCNTs/GC electrode with a wide linear range of 2.5–125μM (R2=0.9996). ► A low working potential (0.25V (SCE)), high sensitivity (414.8μAmM−1cm−2) were achieved the PtPd/MWCNTs/GCE. A new highly catalytic and intensely sensitive amperometric sensor based on PtM (where M=Pd, Ir) bimetallic nanoparticles (NPs) for the rapid and accurate estimation of hydrogen peroxide (H2O2) by electrooxidation in physiological conditions is reported. PtPd and PtIr NPs-decorated multiwalled carbon nanotube nanocatalysts (PtM/MWCNTs) were prepared by a modified Watanabe method, and were characterized by XRD, TEM, ICP, and XAS. The sensors were constructed by immobilizing PtM/MWCNTs nanocatalysts in a Nafion film on a glassy carbon electrode. Both PtPd/MWCNTs and PtIr/MWCNTs assemblies catalyzed the electrochemical oxidation of H2O2. Cyclic voltammetry characterization measurements revealed that both the PtM (M=Pd, Ir)/MWCNTs/GCE possessed similar electrochemical surface areas (∼0.55cm2), and electron transfer rate constants (∼1.23×10−3cms−1); however, the PtPd sensor showed a better performance in H2O2 sensing than did the PtIr counterpart. Explanations were sought from XAS measurements to explain the reasons for differences in sensor activity. When applied to the electrochemical detection of H2O2, the PtPd/MWCNTs/GC electrode exhibited a low detection limit of 1.2μM with a wide linear range of 2.5–125μM (R2=0.9996). A low working potential (0V (SCE)), fast amperometric response (<5s), and high sensitivity (414.8μAmM−1cm−2) were achieved at the PtPd/MWCNTs/GC electrode. In addition, the PtPd/MWCNTs nanocatalyst sensor electrode also exhibited excellent reproducibility and stability. Along with these attractive features, the sensor electrode also displayed very high specificity to H2O2 with complete elimination of interference from UA, AA, AAP and glucose. 出版者： Kidlington: Elsevier B.V 出版日期： 2012-03-15 出處： Biosensors & bioelectronics, 2012-03, Vol.33 (1), p.120-127 版權： 2012 版權： 2015 INIST-CNRS 識別號： ISSN: 0956-5663 識別號： EISSN: 1873-4235 識別號： DOI: 10.1016/j.bios.2011.12.037
Appears in Collections:	[Institute of Materials Science and Engineering] journal & Dissertation

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