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    Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/103553


    Title: Effects of spin speed on the photoelectrochemical properties of Fe2O3 thin films
    Authors: 李勝偉;Lee, Kan-Rong;Hsu, Ya-Ping;Chang, Jeng-Kuei;Lee, Sheng-Wei;Tseng, Chung-Jen;Jang, Jason Shian-Ching
    Contributors: 工學院材料科學與工程研究所
    Keywords: Hydrogen production;Iron oxide;Photoelectrochemical method;Sol-gel;Water spltting
    Date: 2014-01-01
    Issue Date: 2026-04-23 11:32:43 (UTC+8)
    Publisher: Electrochemical Science Group;Elsevier B.V
    Abstract: 摘要: In this work, we report the effects of spin speed on structure and photoelectrochemical properties of Fe2O3 thin films. The Fe2O3 thin films were prepared by sol-gel method and spin coated on fluorine- tin-oxide coated glass substrate. The material properties were examined by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and optical spectroscopy. The photoelectrochemical characteristics were investigated at room temperature. It was demonstrated that heat treatment in air atmosphere greatly enhanced the XRD peak intensity and photocurrent density. Results of XRD show that a-Fe2O3 can be obtained using 500 oC annealing in air. The direct band gaps of the samples obtained from reflectance and transmittance spectra measurement are found to vary from 2.0 to 2.05 eV. The 5000-rpm sample has the maximum photocurrent density of 0.5 mA/cm2 (at 0.5 V vs. Ag/AgCl) under a 300 W Xe lamp system. These good photoelectrochemical results and stability of the Fe2O3 thin film warrants further investigation for broader applications in the future.
    出版者: Elsevier B.V
    出版日期: 2014-12-01
    出處: International Journal of Electrochemical Science, 2014-12, Vol.9 (12), p.7680-7692
    資源來源: Directory of Open Access Journals
    版權: 2014 The Authors. Published by ESG
    識別號: ISSN: 1452-3981
    識別號: EISSN: 1452-3981
    識別號: DOI: 10.1016/S1452-3981(23)10997-7
    Appears in Collections:[Institute of Materials Science and Engineering] journal & Dissertation

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