In situ fabrication of Co0.85Se and Ni0.85Se hierarchical thin films as high-performance counter electrode for dye-sensitized solar cells

Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/103602

Title:	In situ fabrication of Co0.85Se and Ni0.85Se hierarchical thin films as high-performance counter electrode for dye-sensitized solar cells
Authors:	張勝雄;Yao, Yueh-Yun;Chao, Hsi-Jung;Chou, Tzung-Han;Chang, Sheng Hsiung;Wu, Chun-Guey;Ling, Yong-Chien;Chang, Jia-Yaw
Contributors:	理學院光電科學與工程學系
Keywords:	Co0.85Se;Counter electrode;Dye-sensitized solar cell;Hierarchical thin film;Ni0.85Se
Date:	2016-11-01
Issue Date:	2026-04-23 11:33:39 (UTC+8)
Publisher:	Elsevier Ltd.;Elsevier Ltd
Abstract:	摘要： Co0.85Se and Ni0.85Se hierarchical thin films assembled using nanosheets and nanoparticles are deposited in situ on an FTO substrate for an efficient counter electrode in dye-sensitized solar cells. [Display omitted] •The hierarchical structures were grown in situ on FTO by a microwave-assisted method.•The hierarchical structures were consisting of nanoparticles and nanosheets.•The hierarchical structures were used as counter electrode without post-treatment.•Co0.85Se and Ni0.85Se showed good catalytic activity for electrolyte regeneration.•The DSSC with the Co0.85Se showed a highest conversion efficiency of 8.58%. Cobalt selenide (Co0.85Se) and nickel selenide (Ni0.85Se) hierarchical thin films assembled using by nanosheets and nanoparticles, respectively, were fabricated in situ on fluorine-doped tin oxide substrates in a ligand-free environment to prepare counter electrodes (CEs) for dye-sensitized solar cells (DSSCs) consisting of a N719-sensitized nanocrystalline TiO2 film. The Co0.85Se- and Ni0.85Se-based CEs were rapidly synthesized via a microwave-assisted one-step method at 170°C within a short reaction time of 10min. The morphology and structure of the Co0.85Se and Ni0.85Se hierarchical thin films were characterized by means of scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy. The results of electrochemical impedance spectroscopy, cyclic voltammetry, and Tafel polarization measurements showed that both CEs exhibited good electrocatalytic activity and I−/I3− redox reactions and much lower charge-transfer resistance. A power conversion efficiency (PCE) of 8.58% for the Co0.85Se CE-based solar cell was obtained, which is comparable to that of cells using Pt CEs (8.57%); 7.09% PCE was obtained for the Ni0.85Se-based CE. The results suggest that in situ-prepared Co0.85Se-based CEs could be a promising alternative to Pt-based CEs for DSSCs. 出版者： Elsevier Ltd 出版日期： 2016-11-01 出處： Solar energy, 2016-11, Vol.137, p.401-408 版權： 2016 Elsevier Ltd 識別號： ISSN: 0038-092X 識別號： EISSN: 1471-1257 識別號： DOI: 10.1016/j.solener.2016.08.040
Appears in Collections:	[Department of Optics and Photonics] journal & Dissertation

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