A mesoporous aluminium metal-organic framework with 3 nm open pores

Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/103945

Title:	A mesoporous aluminium metal-organic framework with 3 nm open pores
Authors:	楊仲準;Lo, Sheng-Han;Chien, Ching-Hsuan;Lai, Yu-Lun;Yang, Chun-Chuen;Lee, Jey Jau;Raja, Duraisamy Senthil;Lin, Chia-Her
Contributors:	理學院物理學系
Keywords:	Aluminium;Aluminum;Carbon dioxide;coordination polymers;dicarboxylic acids;Displays;hydrogen;ions;ligands;Metal-organic frameworks;nitrogen;oxygen;Porosity;porous media;sorption;Sustainability;Three dimensional;Uptakes
Date:	2013-01-14
Issue Date:	2026-04-23 11:40:29 (UTC+8)
Publisher:	Royal Society of Chemistry
Abstract:	摘要： A mesoporous metal-organic framework of [Al(OH)(SDC)] (CYCU-3) (H sub(2)SDC = 4,4'-stilbenedicarboxylic acid) was synthesised by using Al(iii) ions and H sub(2)SDC under solvothermal conditions. The structure forms 3D mesoporous frameworks in which the carboxylate oxygen on each terminus of the ligand forms octahedral AlO sub(6) by corner-sharing. As verified by N sub(2) sorption measurements, the CYCU-3 exhibits the largest pore volume and open channels (3.0 nm) in the system of Al-MOFs reported to date. This mesoporous Al-MOF also displays highly porous properties and uptake capacities of H sub(2) (8.22 mmol g super(-1) at 77 K and 1 atm) and CO sub(2) (2.83 mmol g super(-1) CO sub(2) at 273 K and 1 atm). 出版日期： 2013-01-01 出處： Journal of materials chemistry. A, Materials for energy and sustainability, 2013-01, Vol.1 (2), p.324-329 資源來源： Royal Society of Chemistry 識別號： ISSN: 2050-7488 識別號： ISSN: 2050-7496 識別號： EISSN: 2050-7496 識別號： DOI: 10.1039/C2TA00030J
Appears in Collections:	[Department of Physics] journal & Dissertation

Files in This Item:

File	Description	Size	Format
index.html		0Kb	HTML	16	View/Open

社群 sharing

Loading...