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    题名: Direct observation of charge re-distribution in a MgB2 superconductor
    作者: 楊仲準;Wu, Sheng Yun;Shih, Po-Hsun;Ji, Jhong-Yi;Chan, Ting-Shan;Yang, Chun Chuen
    贡献者: 理學院物理學系
    关键词: negative thermal expansion;superconductivity;two-phonon effect
    日期: 2016-02-22
    上传时间: 2026-04-23 11:51:41 (UTC+8)
    出版者: IOP Publishing Ltd.;IOP Publishing
    摘要: 摘要: To study the origin of negative thermal expansion effects near the superconducting transition temperature TC in MgB2, low-temperature high-energy synchrotron radiation x-ray diffraction was used to probe the charge redistribution near the boron atoms. Our results reveal that the in-plane hole-distribution of B− hops through the direct orbital overlap of Mg2+ along the c-axis at 50 K and is re-distributed out-of-plane. This study shows that the out-of-plane π-hole distribution plays a dominant role in the possible origin of superconductivity and negative thermal effects in MgB2.
    其他題名: SUST
    其他題名: Supercond. Sci. Technol
    出版者: IOP Publishing
    出版日期: 2016-02-22
    出處: Superconductor science & technology, 2016-02, Vol.29 (4)
    資源來源: Institute of Physics Journals
    版權: 2016 IOP Publishing Ltd
    識別號: ISSN: 0953-2048
    識別號: EISSN: 1361-6668
    識別號: DOI: 10.1088/0953-2048/29/4/045001
    識別號: CODEN: SUSTEF
    显示于类别:[物理學系] 期刊論文

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