Effects of nitrogen and carbon monoxide concentrations on performance of proton exchange membrane fuel cells with Pt-Ru anodic catalyst

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题名:	Effects of nitrogen and carbon monoxide concentrations on performance of proton exchange membrane fuel cells with Pt-Ru anodic catalyst
作者:	陳震宇;Chen, Chen-Yu;Lai, Wei-Hsiang;Yan, Wei-Mon;Chen, Chun-Chi;Hsu, Sui-Wei
贡献者:	工學院能源工程研究所
关键词:	Applied sciences;Dilution effect;Direct energy conversion and energy accumulation;Electrical engineering. Electrical power engineering;Electrical power engineering;Electrochemical conversion: primary and secondary batteries, fuel cells;Energy;Energy. Thermal use of fuels;Equipments for energy generation and conversion: thermal, electrical, mechanical energy, etc;Exact sciences and technology;Fuel cells;Poison effect;Proton exchange membrane fuel cell;Real-time exhaust monitoring;Simulated reformate gas;Voltage fluctuation
日期:	2013-07-08
上传时间:	2026-04-23 11:58:09 (UTC+8)
出版者:	Elsevier;Amsterdam: Elsevier B.V
摘要:	摘要： The reformate gas is one of the commonest solutions to the problem of fuel supply for proton exchange membrane fuel cell systems. Thus, it is important to understand the behaviors of a fuel cell using reformate gases. In this work, effects of nitrogen and carbon monoxide concentrations on unsteady characteristics of a proton exchange membrane fuel cell with the Pt–Ru anodic catalyst are investigated experimentally. Simulated reformate gases with hydrogen, nitrogen and carbon monoxide are employed as the fuel. The experimental data show that a larger dilution effect of nitrogen is noted for cases with lower hydrogen stoichiometric ratios. Furthermore, increasing the carbon monoxide concentration reduces the cell performance because the elevated carbon monoxide adsorption rate results in a severer poison effect. The voltage fluctuating phenomenon is observed at high CO ppm and is due to a periodical change of coverage on the catalyst surface. Meanwhile, it is verified that the voltage fluctuation is accompanied with a periodical change of the anode outlet carbon monoxide concentration. Furthermore, the fluctuating phenomena of voltage and the anode outlet carbon monoxide concentration are more easily triggered in diluted hydrogen than in non-diluted hydrogen. •The dilution effect of N2 is only significant at low H2 stoichiometric ratios.•CO affects PEMFCs in both low current region and high current region.•Voltage fluctuation of a PEMFC with the Pt–Ru catalyst is observed and discussed.•Real-time monitoring of the anode outlet CO concentration is performed.•Fluctuation of the anode outlet CO concentration accompanies voltage fluctuation. 出版者： Amsterdam: Elsevier B.V 出版日期： 2013-12-01 出處： Journal of power sources, 2013-12, Vol.243, p.138-146 資源來源： Elsevier ScienceDirect Journals Complete 版權： 2013 Elsevier B.V. 版權： 2014 INIST-CNRS 識別號： ISSN: 0378-7753 識別號： EISSN: 1873-2755 識別號： DOI: 10.1016/j.jpowsour.2013.06.003 識別號： CODEN: JPSODZ
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