Production of high-performance and improved-durability Pt-catalyst /support for proton-exchange-membrane fuel cells with pulsed laser deposition

NCUIR > Engineering College > Energy of Mechatronics > journal & Dissertation > Item 987654321/104956

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Title:	Production of high-performance and improved-durability Pt-catalyst /support for proton-exchange-membrane fuel cells with pulsed laser deposition
Authors:	曾重仁;Huang, Ting-Wei;Qayyum, Hamza;Lin, Guan-Ren;Chen, Szu-yuan;Tseng, Chung-Jen
Contributors:	工學院能源工程研究所
Keywords:	Anodes;Carbon;catalyst;durability;Gas diffusion;low Pt loading;Platinum;Proton exchange membrane fuel cells;proton-exchange-membrane fuel cell;Pulsed laser deposition;Slurries;Surface area
Date:	2016-05-19
Issue Date:	2026-04-23 12:02:25 (UTC+8)
Publisher:	IOP Publishing Ltd.;IOP Publishing
Abstract:	摘要： Pulsed laser deposition in Ar atmosphere is used to deposit Pt nanoparticles onto gas diffusion layer, and its application to proton-exchange-membrane fuel cell is optimized and characterized. When used at anode side, with a Pt loading of 17 μg cm−2 the fuel-cell current density at 0.6 V reaches 1.08 A cm−2, which is close to that of a cell with the anode made by conventional slurry process using E-TEK Pt /C of 200 μg cm−2 Pt loading. The usage of Pt is decreased by 12 fold. Such a low usage of Pt prepared by pulsed laser deposition can be ascribed to the prevention of forming isolated regions that occurs with Pt /C slurry, good dispersion of Pt particles on support, and small particle sizes of 2-3 nm. Furthermore, using accelerated degradation test, it is found that the pulsed laser deposition sample retains 60% of its initial electrochemical surface area after 5000 potential cycles, much higher than that with E-TEK Pt /C, which retains only 7% of its initial electrochemical surface area. The higher electrochemical durability can be attributed to the higher degree of graphitization in the gas diffusion layer used as compared with the carbon black in E-TEK Pt /C, which leads to stronger binding of the Pt nanoparticles onto the carbon support and stronger corrosion resistance of the carbon support. 其他題名： JPhysD 其他題名： J. Phys. D: Appl. Phys 出版者： IOP Publishing 出版日期： 2016-06-29 出處： Journal of physics. D, Applied physics, 2016-06, Vol.49 (25), p.255601-255607 資源來源： Institute of Physics Journals 版權： 2016 IOP Publishing Ltd 識別號： ISSN: 0022-3727 識別號： EISSN: 1361-6463 識別號： DOI: 10.1088/0022-3727/49/25/255601 識別號： CODEN: JPAPBE
Appears in Collections:	[Energy of Mechatronics] journal & Dissertation

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