Hybridisation at the organic–metal interface: A surface-scientific analogue of hückel’s rule?

Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/104966

Title:	Hybridisation at the organic–metal interface: A surface-scientific analogue of hückel’s rule?
Authors:	森馬丁;Harutyunyan, Hasmik;Callsen, Martin;Allmers, Tobias;Caciuc, Vasile;Blügel, Stefan;Atodiresei, Nicolae;Wegner, Daniel
Contributors:	理學院物理學系
Keywords:	chemical communication;chemical compounds;chemical reactions
Date:	2013-06-06
Issue Date:	2026-04-23 12:02:41 (UTC+8)
Publisher:	Royal Society of Chemistry;England
Abstract:	摘要： We demonstrate that cyclooctatetraene (COT) can be stabilised in different conformations when adsorbed on different noble-metal surfaces due to varying molecule-substrate interactions. While at first glance the behaviour seems to be in accordance with Hückel's rule, a theoretical analysis reveals no significant charge transfer. The driving mechanism for the conformational change is hybridisation at the organic-metal interface and does not necessitate any charge transfer. 其他題名： Chem Commun (Camb) 出版者： England 出版日期： 2013-07-07 出處： Chemical communications (Cambridge, England), 2013-07, Vol.49 (53), p.5993-5995 資源來源： Royal Society of Chemistry 識別號： ISSN: 1359-7345 識別號： ISSN: 1364-548X 識別號： EISSN: 1364-548X 識別號： DOI: 10.1039/c3cc42574f 識別號： PMID: 23719739
Appears in Collections:	[Department of Physics] journal & Dissertation

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