Ultra-low-damage radical treatment for the highly controllable oxidation of large-scale graphene sheets

NCUIR > Engineering College > Energy of Mechatronics > journal & Dissertation > Item 987654321/105038

Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/105038

Title:	Ultra-low-damage radical treatment for the highly controllable oxidation of large-scale graphene sheets
Authors:	蘇清源;Huang, Chi-Hsien;Su, Ching-Yuan;Lai, Chao-Sung;Li, Yen-Cheng;Samukawa, Seiji
Contributors:	工學院能源工程研究所
Keywords:	Adhesion;Carbon;contact angle;Cross-disciplinary physics: materials science;rheology;energy;Exact sciences and technology;free radicals;Fullerenes and related materials;diamonds, graphite;Graphene;graphene oxide;hydrophilicity;Materials science;Oxidation;Oxides;Physics;Radicals;Raman spectroscopy;reactive oxygen species;Specific materials;Stability;X-ray photoelectron spectroscopy;X-rays
Date:	2014-01-01
Issue Date:	2026-04-23 12:04:36 (UTC+8)
Publisher:	Elsevier Ltd.;Kidlington: Elsevier Ltd
Abstract:	摘要： We have used low-damage oxygen radical treatment (O-LDRT)—with chemically reactive radicals generated in a plasma system equipped with a complementary filter—to prepare large-scale graphene oxide sheets with highly controllable levels of oxidation. Raman spectroscopy and X-ray photoelectron spectroscopy revealed that oxidative functionalities were formed on the graphene surfaces in a highly controllable manner and with a wide process window. Contact angle measurements revealed the high hydrophilicity of the large-scale graphene after O-LDRT. We measured the current–voltage characteristics of oxidized double-layer graphene (DLG) sheets to confirm the low degree of damage after using O-LDRT for the oxidation process. For treatment times of up to 5min, the current passing through the DLG sheets remained almost identical to that passing through the corresponding sample that had not been subjected to O-LDRT, indicating that the bottom layer of the graphene sheet remained almost unmodified, whereas a massive number of oxidative functionalities had been formed on the top layer of the graphene sheet; in addition, the adhesion energy increased to approximately twice that of the untreated graphene sheet. 出版者： Kidlington: Elsevier Ltd 出版日期： 2014-07-01 出處： Carbon, 2014-07, Vol.73, p.244-251 資源來源： Elsevier ScienceDirect Journals 版權： 2014 Elsevier Ltd 版權： 2015 INIST-CNRS 識別號： ISSN: 0008-6223 識別號： EISSN: 1873-3891 識別號： DOI: 10.1016/j.carbon.2014.02.060 識別號： CODEN: CRBNAH
Appears in Collections:	[Energy of Mechatronics] journal & Dissertation

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