摘要: Two new calcium and strontium metalorganic frameworks [Ca(SBA)] ( CYCU-1 ) and [Sr(SBA)] ( CYCU-2 ) were prepared by microwave-assisted reactions. Both rigid frameworks are thermally stable up to about 450 C. As verified by N 2 , CO 2 , and H 2 sorption measurements, the thermally activated CYCU-1 and CYCU-2 exhibit significant microporosity. The microwave synthesis has prepared two new porous calcium and strontium MOFs. 出版日期: 2012-01-25 資源來源: Royal Society of Chemistry 識別號: EISSN: 1466-8033 識別號: DOI: 10.1039/c2ce05875h