Efficient Suzuki-Miyaura coupling reaction in water: Stabilized Pd o-Montmorillonite clay composites catalyzed reaction

NCUIR > College of Electrical Engineering & Computer Science > Department of Electrical Engineering > journal & Dissertation > Item 987654321/107150

Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/107150

Title:	Efficient Suzuki-Miyaura coupling reaction in water: Stabilized Pd o-Montmorillonite clay composites catalyzed reaction
Authors:	戴帕克;Borah, Bibek Jyoti;Borah, Subrat Jyoti;Saikia, Kokil;Dutta, Dipak Kumar
Contributors:	資訊電機學院電機工程學系
Keywords:	Catalysis;Catalysts;Clay (material);Joining;Montmorillonite;Porosity;Surface chemistry;Transmission electron microscopy
Date:	2014-01-01
Issue Date:	2026-04-23 13:58:05 (UTC+8)
Publisher:	Elsevier
Abstract:	摘要： The Pdo-nanoparticles, generated into the nanopores of modified Montmorillonite clay, were evaluated for catalytic performance for the Suzuki-Miyaura cross coupling reactions. The modification of Montmorillonite clay was carried out by activating with H2SO4 under controlled conditions for generating nanopores on the surface for serving as a 'Host' for the Pdo-nanoparticles which were prepared in situ by loading of K2PdCl4 through incipient wetness impregnation technique followed by reduction with hydrazine hydrate. The Powder-XRD, SEM-EDX, TEM, N2 adsorption, XPS, etc. analyses were carried out to characterize the stabilized nanoparticles as well as the support. The TEM study reveals that the evenly distributed Pdo-nanoparticles are below 10 nm size and exhibit face centred cubic (fcc) lattice geometry. The supported Pdo-nanoparticles exhibit efficient heterogeneous catalytic performance for the Suzuki-Miyaura coupling reactions between different organoboronic acids and aryl halides for preparing the cross-coupling products in 94% isolated yield (maximum) and 100% selectivity in water under ligand free conditions. The nanocatalysts could be recycled at least three consecutive runs with a little loss of their catalytic activities. 出版日期： 2014-01-01 出處： Applied catalysis. A, General, 2014-01, Vol.469, p.350-356 資源來源： Elsevier ScienceDirect Journals Complete 識別號： ISSN: 0926-860X 識別號： DOI: 10.1016/j.apcata.2013.10.018
Appears in Collections:	[Department of Electrical Engineering] journal & Dissertation

Files in This Item:

File	Description	Size	Format
index.html		0Kb	HTML	13	View/Open

社群 sharing

Loading...