Synthesis and herbicidal activity of novel N-allyloxy/propargyloxy aryloxyphenoxy propionamide derivatives

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Title:	Synthesis and herbicidal activity of novel N-allyloxy/propargyloxy aryloxyphenoxy propionamide derivatives
Authors:	劉愛萍;Liu, Qixing;Huang, Mingzhi;Liu, Aiping;Hu, Aixi;Lei, Manxiang;Ren, Yeguo;Huang, Lu
Contributors:	總教學中心語言中心
Keywords:	Analytical Chemistry;Chemistry;Chemistry and Materials Science;Chemistry/Food Science;IC50;Inorganic Chemistry;LC-MS;Organic Chemistry;Physical Chemistry;合成;小说;苯氧基;酰胺类化合物;酰胺衍生物;除草活性
Date:	2016-04-01
Issue Date:	2026-04-23 14:28:03 (UTC+8)
Publisher:	Springer International Publishing AG;Changchun: Jilin University and The Editorial Department of Chemical Research in Chinese Universities
Abstract:	摘要： A series of novel N-allyloxy/propargyloxy aryloxyphenoxy propionamide compounds was designed and prepared. The structures of the synthesized compounds were confirmed by means of 1H NMR, 13C NMR, LC-MS, elemental analysis and IR. The bioassay results indicate that when against Digitaria sanguinalis and Echinochloa crus-galli, （R）-N-（propargyloxy）-2-{4-[（6-chloroquinoxalin-2-yl） oxy] phenoxy}propanamide（1m）（IC50=6.8 and 6.5 g/hm2, respectively） and （R）-N-（allyloxy）-2-{4-[（6-chloroquinoxalin-2-yl） oxy]phenoxy}propanamide（1r）（IC50=7.4 and 6.0 g/hm2, respectively） are much more effective than commercial aryloxyphenoxypropionic ester herbicide clodinafop-propargyl（IC50=46.5 and 14.6 g/hm2, respectively）. The results of crop selectivity show that compounds 1m and 1r are safe to soybean, rape and cotton and can be used as herbicides for soybean, rape and cotton crop. 其他題名： Chem. Res. Chin. Univ 其他題名： Chemical Research in Chinese University 出版者： Changchun: Jilin University and The Editorial Department of Chemical Research in Chinese Universities 出版日期： 2016-04-01 出處： Chemical research in Chinese universities, 2016-04, Vol.32 (2), p.188-194 版權： Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH 2016 識別號： ISSN: 1005-9040 識別號： EISSN: 2210-3171 識別號： DOI: 10.1007/s40242-016-5415-0
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