Electrochemical Society, Inc.;The Electrochemical Society
摘要:
摘要： Pressurization influence on electrochemical impedance spectra (EIS) of both anode-supported and electrolyte-supported cells (ASC and ESC) are measured and compared using a high-pressure SOFC facility. In it both ASC and ESC apply the same single-cell setup, a planar full cell having 40 × 40 mm2 effective reactive area sandwiched by a pair of rib-channel flow distributors (interconnectors) on both anode and cathode, using the same flow rates (Qanode = 0.5 slpm H2 + 0.4 slpm N2 and Qcathode = 0.9 slpm air) at 850°C, with five different pressures (1 ∼ 5 atm). It is found that ASC is more sensitive to pressurization than ESC, of which power densities of ASC/ESC at 0.7 V increase from 309/193 mW cm−2 to 476/250 mW cm−2, as p increases from 1 atm to 5 atm, corresponding to a 54%/30% increase. This result is explained by EIS measured data, in which both ohmic and polarization resistances of ASC are smaller than that of ESC. Moreover, the ohmic resistance is independent of pressurization for both ASC and ESC, remaining constant regardless of either unloaded or loaded conditions, while the polarization resistance decreases noticeably with increasing pressure for both ASC and ESC. 其他題名： J. Electrochem. Soc 出版者： The Electrochemical Society 出版日期： 2015-01-01 出處： Journal of the Electrochemical Society, 2015-01, Vol.162 (1), p.F172-F177 資源來源： Institute of Physics (IOP) Journals 版權： 2014 The Electrochemical Society 識別號： ISSN: 0013-4651 識別號： EISSN: 1945-7111 識別號： DOI: 10.1149/2.0041503jes
