Preparation of polyacrylonitrile/ferrous chloride composite nanofibers by electrospinning for efficient reduction of Cr(VI)

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Title:	Preparation of polyacrylonitrile/ferrous chloride composite nanofibers by electrospinning for efficient reduction of Cr(VI)
Authors:	林進榮;Zhou, Shilin;Liu, Fang;Zhang, Qian;Chen, Bor-Yann;Lin, Chin-Jung;Chang, Chang-Tang
Contributors:	工學院環境工程研究所
Keywords:	Adsorption;Chlorides;Chromium;Electrospinning;Mathematical models;Nanofibers;Polyacrylonitriles;Surface chemistry
Date:	2015-08-01
Issue Date:	2026-04-23 15:08:38 (UTC+8)
Publisher:	American Scientific Publishers;26650 The Old Road, Suite 208, Valencia, California 91381-0751, USA: American Scientific Publishers
Abstract:	摘要： In this study, A novel adsorbent material of polyacrylonitrile (PAN)/ferrous chloride (FeCl2) composite nanofibers is prepared by electrospinning, a simple and effective method. The obtained composite nanofibers have a non-uniform morphology and structure and a large specific surface area of 13.8 m2 g−1. Fourier transform infrared spectroscopy (FTIR) revealed that Fe2+ was successful introduced into the composite nanofibers. Furthermore, the PAN/FeCl2 composite nanofibers exhibited excellent performance in Cr removal, especially when reacted with reduction from a Cr(VI) standard containing solution, which has much faster removal efficiency than the previous report of Lin et al. (2011). The results of the adsorption isotherm show that the data fitted well to the Langmuir isotherm model. The maximum adsorption of chromium ions composite nanofibers is 108 mgCr/gFeCl2. An attempted model prediction of the transient dynamics of adsorption-desorption elucidated the feasible kinetic analysis of Cr6+ from the PAN/FeCl2 composite nanofibers. This kinetic modeling can be used both for adsorption of heavy metals wastewater and for organic-adsorption and biosorption of diverse wastewaters. The PAN/FeCl2 composite nanofibers producted in this study exhibit high efficiency in Cr(VI) removal from wastewater, and may be used as a reference for future investigation. 其他題名： J Nanosci Nanotechnol 出版者： 26650 The Old Road, Suite 208, Valencia, California 91381-0751, USA: American Scientific Publishers 出版日期： 2015-08-01 出處： Journal of nanoscience and nanotechnology, 2015-08, Vol.15 (8), p.5823-5832 識別號： ISSN: 1533-4880 識別號： EISSN: 1533-4899 識別號： DOI: 10.1166/jnn.2015.10271 識別號： PMID: 26369157
Appears in Collections:	[Graduate Institute of Environmental Engineering ] journal & Dissertation

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