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    Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/108858


    Title: Visible-light photocatalytic conversion of CO2 to methanol using dye-sensitized mesoporous photocatalysts
    Authors: 林進榮;Lin, C-J;Liou, Y-H;Chen, S-Y;Tsai, M-C
    Contributors: 工學院環境工程研究所
    Keywords: Absorption;Atomic absorption spectroscopy;Carbon dioxide;Gravimetric analysis;Halides;Microscopy;Nitrogen;Sorption;X-ray diffraction
    Date: 2012-01-01
    Issue Date: 2026-04-23 15:10:17 (UTC+8)
    Publisher: Chinese Institute of Environmental Engineering (CIEnvE)
    Abstract: 摘要: Dye-sensitized TiO sub(2)/SBA-15 was prepared using a two-step route, including grafting a thin layer of TiO sub(2) onto SBA-15 and then impregnating it with 2,9-dichloro quinacridone (DCQ) molecules. The prepared material was characterized by X-ray diffraction (XRD), High-resolution transmission electron microscopy, atomic absorption spectroscopy, nitrogen sorption isotherm, Thermal gravimetric analyses, UV-Vis. The XRD patterns of SBA-15 and TiO sub(2)/SBA-15 exhibit a peek of (100), which is the characteristic of a highly ordered hexagonal structure. UV-Vis spectrum of TiO sub(2)/SBA-15 shows the band edge of 400 nm. After functionalized by DCQ, a new band between 500 and 600 nm emerges, which enables the catalyst to absorb visible light. For photocatalytic reduction of CO sub(2) into methanol in water under 100 W halide lamp illumination, DCQ-TiO sub(2)/SBA-15 exhibits superior methanol yield (0.44 mu mol g super(-1)-cat h super(-1)) than that (0.16 mu mol g super(-1)-cat h super(-1)) of DCQ-P25 TiO sub(2
    出版日期: 2012-05-01
    出處: Journal of environmental engineering and management, 2012-05, Vol.22 (3), p.167-172
    識別號: ISSN: 1022-7636
    識別號: EISSN: 1022-7636
    Appears in Collections:[Graduate Institute of Environmental Engineering ] journal & Dissertation

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