Interfacial characterization of nickel-yttria-stabilized zirconia cermet anode/interconnect joints with Ag-Pd-Ga active filler for use in solid-oxide fuel cells

NCUIR > Engineering College > Departmant of Mechanical Engineering > journal & Dissertation > Item 987654321/108931

Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/108931

Title:	Interfacial characterization of nickel-yttria-stabilized zirconia cermet anode/interconnect joints with Ag-Pd-Ga active filler for use in solid-oxide fuel cells
Authors:	李雄;Chao, Chih-Long;Chu, Chun-Lin;Fuh, Yiin-Kuen;Hsu, Ray-Quen;Lee, Shyong;Cheng, Yung-Neng
Contributors:	工學院機械工程學系
Keywords:	Anodes;Cermets;Fillers;Interconnect;Interconnections;Joint strength;Nickel;Scanning electron microscopy;Silver base alloys;Solid oxide fuel cell (SOFC);X-ray diffraction;Zirconium dioxide
Date:	2015-01-01
Issue Date:	2026-04-23 15:16:12 (UTC+8)
Publisher:	Elsevier Ltd.;Elsevier Ltd
Abstract:	摘要： Nickel–yttria-stabilized zirconia cermet anode (Ni–YSZ)/interconnect joints with silver–palladium–gallium (Ag–9Pd–9Ga) active fillers are prepared by vacuum brazing. The joint structure and microstructure are analyzed by X-ray diffraction (XRD) and scanning electron microscopy coupled with energy dispersive spectroscopy (SEM/EDS), and by using an electron probe microanalyzer (EPMA). SEM observations of the joint show no cracks near the interface, confirming the compatibility of the Ag–9Pd–9Ga filler with a different anode and interconnect. The XRD pattern of the joint specimens oxidized at 800 °C for 250 h shows Cr2O3 and (Mn,Cr)3O4 surface layers. EPMA analysis of the cell/Ag–9Pd–9Ga/alloys joint at the cross section shows Cr, O, Fe, Zr, Ni, Ag, Pd, Ga, Y, and Mn. Overall, the results indicate that the bonding between metal and cermet is well established and the interface is smooth. By correlating the XRD and EPMA analysis results, we also analyzed the possible stages during joint oxidation. The joint strength was evaluated at 25 and 800 °C under shear and tensile loading conditions, respectively, and the brazed Ag–9Pd–9Ga sealant compared favorably with the commercially available glass-ceramic GC-9 counterpart. •A technique is developed to measure strength of Ni–YSZ/Ag–Pd–Ga/metal interconnect joint.•800 °C for 500 h oxidation do not result in the formation of cracks at the interface between Ag–Pd–Ga/metal interconnect joint.•Ag–Pd–Ga seal on metal interconnects than those for the glass-ceramic counterpart GC-9. 出版者： Elsevier Ltd 出版日期： 2015-01-21 出處： International journal of hydrogen energy, 2015-01, Vol.40 (3), p.1523-1533 資源來源： Elsevier ScienceDirect Journals Complete 版權： 2014 Hydrogen Energy Publications, LLC. 識別號： ISSN: 0360-3199 識別號： EISSN: 1879-3487 識別號： DOI: 10.1016/j.ijhydene.2014.11.028
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