Synthesis of Novel Organic-Inorganic Hybrid Compounds: Lanthanide Phosphites Incorporating a Squarate Ligand

Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/28348

Title:	Synthesis of Novel Organic-Inorganic Hybrid Compounds: Lanthanide Phosphites Incorporating a Squarate Ligand
Authors:	Wang,CM;Lii,KH
Contributors:	中央大學
Keywords:	HYDROTHERMAL SYNTHESIS;MAGNETIC-PROPERTIES;CRYSTAL-STRUCTURE;FRAMEWORK STRUCTURES;SPECTROSCOPY;OXALATES
Date:	2009
Issue Date:	2010-06-29 19:46:42 (UTC+8)
Publisher:	化學研究所
Abstract:	The first examples of metal phosphite incorporating a squarate anion as a ligand have been synthesized by a hydrothermal method. Their structures contain zigzag chains of edge-sharing LnO(8) (Ln = Sm, Eu, and Gd) square antiprisms connected by phosphite groups to form 2D layers, which are pillared by squarate ligands into a 3D framework. The photoluminescence properties of the Eu compound have also been studied,
Relation:	INORGANIC CHEMISTRY
Appears in Collections:	[Graduate Institute of Chemistry] journal & Dissertation

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