Organically templated inorganic/organic hybrid materials: Synthesis and structures of (C4H12N2)[Fe-4(II)(C2O4)(3)(HPO4)(2)] and (C5H14N2)[Fe-2(III)(C2O4) (HPO4)(3)]

Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/28368

Title:	Organically templated inorganic/organic hybrid materials: Synthesis and structures of (C4H12N2)[Fe-4(II)(C2O4)(3)(HPO4)(2)] and (C5H14N2)[Fe-2(III)(C2O4) (HPO4)(3)]
Authors:	Lin,HM;Lii,KH;Jiang,YC;Wang,SL
Contributors:	中央大學
Keywords:	IRON PHOSPHATE;HYDROTHERMAL SYNTHESIS;CRYSTAL-STRUCTURE;OPEN-FRAMEWORK;NETWORK
Date:	1999
Issue Date:	2010-06-29 19:47:13 (UTC+8)
Publisher:	化學研究所
Abstract:	Hydrothermal treatment of FeCl2. 4H(2)O (or FeCl3. 6H(2)O) and piperazine (or 2-methylpiperazine) with H3PO4 and H2C2O4 in H2O yields two organically templated compounds. The 3-D frameworks are constructed from Fe-II-O (or Fe-III-O) polyhedra and two different ligands, phosphate and oxalate, both coordinated to the iron atoms. The structure of the Fe-III compound is shown.
Relation:	CHEMISTRY OF MATERIALS
Appears in Collections:	[Graduate Institute of Chemistry] journal & Dissertation

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