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    Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/28373


    Title: Synthesis, crystal structure and Ga-71 MAS NMR spectroscopy of a novel gallium phosphatooxalate: [Ga-5(OH)(2)(C10H9N2)(C2O4)(PO4)(4)]center dot 2H(2)O
    Authors: Chen,CY;Chu,PP;Lii,KH
    Contributors: 中央大學
    Keywords: MOLECULAR-SIEVES;PHOSPHATES;FRAMEWORK;SOLIDS
    Date: 1999
    Issue Date: 2010-06-29 19:47:20 (UTC+8)
    Publisher: 化學研究所
    Abstract: The synthesis and characterization of a novel three-dimensional gallium phosphatooxalate is described; the structure consists of GaO4 tetrahedra and GaO6 octahedra linked by phosphate and oxalate groups to form two-dimensional sheets between which are GaO4N square pyramids, generating tunnels in which the monoprotonated 4,4'-bipyridine molecules reside; Ga-71 MAS NMR confirms the presence of four-, five- and six-coordinate Ga atoms.
    Relation: CHEMICAL COMMUNICATIONS
    Appears in Collections:[化學研究所] 期刊論文

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