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    题名: Room temperature dedoping of conducting poly-3-alkylthiophenes
    作者: Wu,CG;Chan,MJ;Lin,YC
    贡献者: 中央大學
    关键词: CONJUGATED POLYMERS;ENHANCED STABILITY;POLY(3-ALKYLTHIOPHENES);POLY(3-OCTYLTHIOPHENE);STATE;POLYTHIOPHENES;SPECTROSCOPY;FILMS
    日期: 1998
    上传时间: 2010-06-29 19:47:45 (UTC+8)
    出版者: 化學研究所
    摘要: Thin films of FeCl3 doped polyalkylthiophene (side chain length from 6 to 18) have been automatically dedoped in ambient atmosphere at room temperature, The dedoping rate Is dependent upon the side chain length, dopant, ambient lighting and film morphology. The maximum dedoping rate occurred in the first 30 min and dropped off rapidly after-one hour. Dedoping is the reversible process of doping, bipolarons;being reduced to polarons and then to the neutral state. The production of Fe2+ and HCl during the dedoping process indicates that moisture acted as the reducing agent. In other words, bipolarons were reduced by H2O to polarons. Polarons subsequently disproportionate to bipolarons and neutral polymer or reduced Fe3+ to Fe2+. Protons, produced from the oxidition of H2O, react with FeCl4- or FeCl42- to product: HCl and iron complexes.
    關聯: JOURNAL OF MATERIALS CHEMISTRY
    显示于类别:[化學研究所] 期刊論文

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