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    請使用永久網址來引用或連結此文件: http://ir.lib.ncu.edu.tw/handle/987654321/39186


    題名: Polymer brush under strong shear
    作者: Lai,PY;Lai,CY
    貢獻者: 物理研究所
    關鍵詞: MONTE-CARLO;HYDRODYNAMIC INTERACTIONS;GRAFTED POLYMERS;LAYERS;FLOW;SURFACES;FORCES;CHAIN
    日期: 1996
    上傳時間: 2010-07-08 14:07:38 (UTC+8)
    出版者: 中央大學
    摘要: End-grafted polymer brush exposed to strong shear solvent flow is studied. Under strong enough shear flow, the shear force is nonlinear with the blob size depending on the shear force and not on the monomer volume fraction phi. We derive the crossover force scale separating the weak and strong shear regime. The velocity profile of the flow, v(z), inside and above the brush is calculated analytically by treating the flow as in a porous medium and solving the Brinkman equation. The solution of the velocity profile is then combined with nonequilibrium Monte Carlo simulation data, which allow a self-consistent determination of the chain end-to-end length and the incline angle of the chain. We derive the scaling form for the chain positions x(n) for the nth monomer and verified by our simulation data. We further obtain analytical expression for x(n) in terms of the effective viscosity of the model.
    關聯: PHYSICAL REVIEW E
    顯示於類別:[物理研究所] 期刊論文

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