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    請使用永久網址來引用或連結此文件: http://ir.lib.ncu.edu.tw/handle/987654321/39271


    題名: BINARY MIXTURE OF GRAFTED POLYMER-CHAINS - A MONTE-CARLO SIMULATION
    作者: LAI,PY
    貢獻者: 物理研究所
    關鍵詞: DYNAMICS;BRUSHES;LAYERS
    日期: 1994
    上傳時間: 2010-07-08 14:10:26 (UTC+8)
    出版者: 中央大學
    摘要: Grafted polymer layer composed of a binary mixture of incompatible chains under good solvent condition is simulated using the bond-fluctuation model. The equilibrium structures of the partially phase separated states are investigated as a function of the incompatibility and relative fraction by monitoring the monomer distribution functions and the chain linear dimensions. For the case of symmetric binary mixtures, we observe the chains of the same type cluster together laterally forming the ''ripple state'' while the layer state is never observed. For asymmetric mixtures, layer structures with the minority chains staying further away from the grafting plane are observed which is in contrary to previous theoretical predictions. The heights of both the minority and majority chains in the layer state are shown to be proportional to their chain lengths.
    關聯: JOURNAL OF CHEMICAL PHYSICS
    顯示於類別:[物理研究所] 期刊論文

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