金屬矽酸鹽之合成、結構與性質研究; Synthesis, Crystal Structures and Properties of Metal Silicates

Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/45197

Title:	金屬矽酸鹽之合成、結構與性質研究;Synthesis, Crystal Structures and Properties of Metal Silicates
Authors:	李光華
Contributors:	化學學系
Keywords:	矽酸鹽;磷酸鹽;水熱法;熔鹽法;熱離子液法;晶體結構;silicate;phosphate;hydrothermal;flux growth;ionothermal;crystal structure;化學類
Date:	2007-07-01
Issue Date:	2010-12-21 17:17:46 (UTC+8)
Publisher:	行政院國家科學委員會
Abstract:	合成具有開闊結構的無機化合物是一個很有趣的研究課題，因為這些化合物不僅具有豐富的結構化學，而且在觸媒、離子交換與吸附應用上具有潛在價值。此計畫將置重點於合成具有開闊架構含有磷酸根與多牙基有機配位基的配位聚合物，過渡金屬、13 族元素、鑭系元素與鈾金屬矽酸鹽。合成方法主要是中溫水熱法、高溫高壓水熱法、熔鹽法與熱離子液法。除了合成與結構鑑定外，也研究固態核磁共振、發光性質、離子交換與磁性。 Open-framework inorganic compounds are of great interest not only for their rich structural chemistry, but also for potential applications in catalysis, ion exchange and sorption. We propose to synthesize open-framework coordination polymers containing phosphate (or phosphonate) and multi-dentate organic ligands, and silicates of transition metals, group 13 elements, lanthanides and uranium. The synthetic methods include mild hydrothermal reactions in Teflon-lined autoclaves at 100-200 oC, high-temperature, high-pressure hydrothermal reactions in gold ampoules contained in a high-pressure reaction vessel at 500-600 oC and 1000-2000 atm, high-temperature solid state reactions using fluxes, and ionothermal methods using ionic liquids as solvents. Their crystal structures, solid-state NMR, photoluminescence properties, ion-exchange properties, and magnetic properties will be studied. 研究期間：9508 ~ 9607
Relation:	財團法人國家實驗研究院科技政策研究與資訊中心
Appears in Collections:	[Department of Chemistry] Research Project

Files in This Item:

File	Description	Size	Format
index.html		0Kb	HTML	447	View/Open

社群 sharing

Loading...