(1)H NMR Spectroscopic Study of the Solution Structure of a Conjugated Polymer

NCU Institutional Repository > 理學院 > 化學學系 > 期刊論文 > Item 987654321/50671

請使用永久網址來引用或連結此文件: http://ir.lib.ncu.edu.tw/handle/987654321/50671

題名:	(1)H NMR Spectroscopic Study of the Solution Structure of a Conjugated Polymer
作者:	Rahman,MH;Chen,HL;Chen,SA;Chu,PPJ
貢獻者:	化學學系
日期:	2010
上傳時間:	2012-03-27 18:07:28 (UTC+8)
出版者:	國立中央大學
摘要:	The structure of poly[2-methoxy-5-(2'-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) solutions with a number of common deuterated organic solvents was studied by means of (1)H NMR spectroscopy The resonance bands of the polymer backbone protons appear at much lower frequencies in CDCl(3) compared to their positions in aromatic solvents This has been attributed to the pi-pi self-stacking interaction of the polymer segments in the aliphatic solvent, which is replaced by a polymer-solvent pi-pi interaction in the aromatic solvents. In mixed solvent systems with an aliphatic solvent component and an aromatic one, the intensifies of the polymer resonances pass through a maximum at intermediate solvent compositions. This has been attributed to the minimum aggregation tendency of the polymer at these solvent compositions. The results suggest that a mixed solvent system constituting an aliphatic component and an aromatic component might be a choice for casting films of hairy-rod type conjugated polymers if minimization of aggregate domains in the films is desired.
關聯:	JOURNAL OF THE CHINESE CHEMICAL SOCIETY
顯示於類別:	[化學學系] 期刊論文

文件中的檔案:

檔案	描述	大小	格式	瀏覽次數
index.html		0Kb	HTML	1357	檢視/開啟

在NCUIR中所有的資料項目都受到原著作權保護.

社群 sharing