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    Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/99774


    Title: Effect of groundwater chemistry on the swelling behavior of a Ca-bentonite for deep geological repository
    Authors: 黃偉慶;Chen, Wen-Chuan;Huang, Wei-Hsing
    Contributors: 工學院土木工程學系
    Keywords: Bentonite;Geological repository;Groundwater chemistry;Swelling
    Date: 2013-06-27
    Issue Date: 2026-04-21 13:35:16 (UTC+8)
    Publisher: Elsevier Ltd.;Elsevier Ltd
    Abstract: 摘要: •We evaluate the swelling behavior of a locally available clay.•Free swells in NaCl, CaCl2, and Na2SO4 solutions at various concentration levels.•The formation of quasi-crystals reduces the swelling strain of Ca-bentonite. The swelling properties of buffer material for high level radioactive waste repository in a near-field environment are of particular importance for achieving the low permeability sealing function. In this study, the free swelling behavior of a potential buffer material Zhisin clay is evaluated under simulated groundwater conditions such as immersion in NaCl, CaCl2, and Na2SO4 solutions at various concentrations. Experimental results indicate that Zhisin clay, being a Ca-bentonite, exhibits reduced swelling strain in salt solutions. The amount of decrease in swelling strain upon saline water intrusion is affected by both the type and concentration of electrolyte. At the same concentration, the swelling strains in CaCl2 solution are lower than those in NaCl solution due to the quasi-crystals formed in the presence of calcium ions. Also, the swells in Na2SO4 solution are found to be lower than those in NaCl solution. This is attributed to the precipitation of CaSO4, which acts as binding agent and results in aggregation of clay particles.
    出版者: Elsevier Ltd
    出版日期: 2013
    出處: Physics and chemistry of the earth. Parts A/B/C, 2013, Vol.65, p.42-49
    版權: 2013 Elsevier Ltd
    識別號: ISSN: 1474-7065
    識別號: EISSN: 1873-5193
    識別號: DOI: 10.1016/j.pce.2013.05.012
    Appears in Collections:[Department of Civil Engineering] journal & Dissertation

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