Porous MnO 2 hollow cubes as new nanoscaffold materials for the dehydrogenation promotion of ammonia-borane (AB)

NCUIR > College of Earth Sciences > Department of Atmospheric Sciences > journal & Dissertation > Item 987654321/99822

Please use this identifier to cite or link to this item: https://ir.lib.ncu.edu.tw/handle/987654321/99822

Title:	Porous MnO 2 hollow cubes as new nanoscaffold materials for the dehydrogenation promotion of ammonia-borane (AB)
Authors:	鄭芳怡;Yang, Zaixing;Liang, Jing;Cheng, Fangyi;Tao, Zhanliang;Chen, Jun
Contributors:	地球科學學院大氣科學學系
Keywords:	Ammonia borane;Chemistry;Colloidal state and disperse state;Dehydrogenation;Emulsions. Microemulsions. Foams;Exact sciences and technology;General and physical chemistry;Hydrogen storage;Nanoconfinement effect;Porous materials;Porous MnO2 hollow cubes
Date:	2012-10-01
Issue Date:	2026-04-21 13:36:55 (UTC+8)
Publisher:	Elsevier;San Diego, CA: Elsevier Inc
Abstract:	摘要： [Display omitted] ► Porous MnO2 hollow cubes have been synthesized. Different loading levels of AB loaded in MnO2 were considered. ► The dehydrogenation performance of the MnO2/AB system was investigated. ► MnO2/AB with the mass ratio of 3:1 showed the best dehydrogenation properties. We report on the synthesis of porous MnO2 hollow cubes via a microemulsion method and their application as new nanoscaffold materials to confine ammonia borane (AB) for enhancing the dehydrogenation process. Different loading levels of AB loaded in MnO2 are investigated. The results show that porous MnO2 hollow cubes have a high surface area of 297.9m2/g and AB is uniformly loaded in the porous MnO2. It is also found that in the examined system, MnO2/AB with the mass ratio of 3:1 (3MnO2/AB) displays the best dehydrogenation properties. The onset temperature of the dehydrogenation of 3MnO2/AB sample is as low as 60°C with the peak temperature at 97°C, while the byproducts such as borazine, diborane and NH3 are completely suppressed. Furthermore, 3MnO2/AB sample can release about 0.9 equivalent H2 within 90min at 85°C. This study indicates that AB loaded in porous MnO2 is an effective approach in modifying the properties of AB with favorable dehydrogenation. 出版者： San Diego, CA: Elsevier Inc 出版日期： 2012-10-01 出處： Microporous and mesoporous materials, 2012-10, Vol.161, p.40-47 資源來源： ScienceDirect - Freedom Collection 版權： 2012 Elsevier Inc. 版權： 2015 INIST-CNRS 識別號： ISSN: 1387-1811 識別號： EISSN: 1873-3093 識別號： DOI: 10.1016/j.micromeso.2012.05.018
Appears in Collections:	[Department of Atmospheric Sciences] journal & Dissertation

Files in This Item:

File	Description	Size	Format
index.html		0Kb	HTML	17	View/Open

社群 sharing

Loading...