In-canopy gas-phase chemistry during CABINEX 2009: Sensitivity of a 1-D canopy model to vertical mixing and isoprene chemistry

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题名:	In-canopy gas-phase chemistry during CABINEX 2009: Sensitivity of a 1-D canopy model to vertical mixing and isoprene chemistry
作者:	谷邁世;Bryan, A. M.;Bertman, S. B.;Carroll, M. A.;Dusanter, S.;Edwards, G. D.;Forkel, R.;Griffith, S.;Guenther, A. B.;Hansen, R. F.;Helmig, D.;Jobson, B. T.;Keutsch, F. N.;Lefer, B. L.;Pressley, S. N.;Shepson, P. B.;Stevens, P. S.;Steiner, A. L.
贡献者:	地球科學學院大氣科學學系
关键词:	Atmospheric chemistry;Canopies;Deciduous forests;Environmental Sciences;Isoprene;Mixed forests;Monoterpenes;Ocean, Atmosphere;Organic compounds;Oxidation;Sciences of the Universe;VOCs;Volatile organic compounds
日期:	2012-11-19
上传时间:	2026-04-21 13:37:21 (UTC+8)
出版者:	European Geosciences Union;Katlenburg-Lindau: Copernicus GmbH
摘要:	摘要： Abstract. Vegetation emits large quantities of biogenic volatile organic compounds (BVOC). At remote sites, these compounds are the dominant precursors to ozone and secondary organic aerosol (SOA) production, yet current field studies show that atmospheric models have difficulty in capturing the observed HOx cycle and concentrations of BVOC oxidation products. In this manuscript, we simulate BVOC chemistry within a forest canopy using a one-dimensional canopy-chemistry model (Canopy Atmospheric CHemistry Emission model; CACHE) for a mixed deciduous forest in northern Michigan during the CABINEX 2009 campaign. We find that the base-case model, using fully-parameterized mixing and the simplified biogenic chemistry of the Regional Atmospheric Chemistry Model (RACM), underestimates daytime in-canopy vertical mixing by 50–70% and by an order of magnitude at night, leading to discrepancies in the diurnal evolution of HOx, BVOC, and BVOC oxidation products. Implementing observed micrometeorological data from above and within the canopy substantially improves the diurnal cycle of modeled BVOC, particularly at the end of the day, and also improves the observation-model agreement for some BVOC oxidation products and OH reactivity. We compare the RACM mechanism to a version that includes the Mainz isoprene mechanism (RACM-MIM) to test the model sensitivity to enhanced isoprene degradation. RACM-MIM simulates higher concentrations of both primary BVOC (isoprene and monoterpenes) and oxidation products (HCHO, MACR+MVK) compared with RACM simulations. Additionally, the revised mechanism alters the OH concentrations and increases HO2. These changes generally improve agreement with HOx observations yet overestimate BVOC oxidation products, indicating that this isoprene mechanism does not improve the representation of local chemistry at the site. Overall, the revised mechanism yields smaller changes in BVOC and BVOC oxidation product concentrations and gradients than improving the parameterization of vertical mixing with observations, suggesting that uncertainties in vertical mixing parameterizations are an important component in understanding observed BVOC chemistry. 出版者： Katlenburg-Lindau: Copernicus GmbH 出版日期： 2012-09-28 出處： Atmospheric Chemistry and Physics, 2012-09, Vol.12 (18), p.8829-8849 資源來源： Agricultural & Environmental Science Collection 版權： COPYRIGHT 2012 Copernicus GmbH 版權： Copyright Copernicus GmbH 2012 版權： licence_http://creativecommons.org/publicdomain/zero 識別號： ISSN: 1680-7324 識別號： ISSN: 1680-7316 識別號： EISSN: 1680-7324 識別號： DOI: 10.5194/acp-12-8829-2012
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