紫外線固化含改質金屬有機框架材料混合基質薄膜應用於產品包裝

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姓名

賴弘宇(HONG-YU LAI) 查詢紙本館藏

畢業系所

化學工程與材料工程學系

論文名稱

紫外線固化含改質金屬有機框架材料混合基質薄膜應用於產品包裝
(UV Curing Mixed Matrix Membrane Containing Modified Metal-Organic Frameworks for Product Packaging)

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至系統瀏覽論文 (2028-6-30以後開放)

摘要(中)

包裝在許多領域扮演著重要的角色，例如食品、藥品、電子產品等。此外，氧氣阻隔性能有時是包裝材料最關鍵的討論因素。隨著技術的進步和行業的進步，我們需要開發智能包裝以應用於不同的領域。
混合基質薄膜 (MMMs) 常用於分離混合氣體。此外，混合基質薄膜通常是通過澆鑄方法合成的，即將前體溶液倒在板上，然後通過蒸發去除溶劑。這項研究的重點是另一種通過紫外線固化製造膜的方法，與熱固化聚合物塗層相比，它具有明顯的優勢。除了固化時間快之外，紫外線固化還涉及較低的資本投資和運營成本，並且是一種無溶劑工藝。
為了開發一種易於加工的合適的多功能包裝材料，我們在氧化石墨烯上原位生長了正八面體的 UiO-66-NH2，以此作為填料。並使用快速的 UV 固化聚合物聚乙二醇二丙烯酸酯和無溶劑工藝來製造混合基質薄膜。並利用 X 射線衍射儀 (XRD)、傅里葉轉換紅外光譜 (FTIR)、超高解析冷場發射掃描式電子顯微鏡 (SEM)、動態光散射 (DLS)、熱重分析 (TGA)、Brunauer-Emmett-Teller (BET)、拉曼光譜、機械性能、單一氣體滲透實驗用於表徵填料和膜。

摘要(英)

Packaging plays an important role in our daily life in many fields, such as food, medicine, and electronic products. Besides, oxygen barrier performance is sometimes the most critical discussion factor for packaging materials. With advances in technology and industry progress, we need to develop intelligent packaging to apply to different fields.
Mixed matrix membranes (MMMs) are popular for separating mixed gases. Moreover, MMMs are synthesized using a casting method, wherein the precursor solution is poured onto a plate, and then the solvent is removed through evaporation. This research focuses on another way to fabricate membranes via UV curing, which provides distinct advantages compared to thermally cured polymer coatings. In addition to the fast curing time, UV curing also involves lower capital investment and operating costs and is a solvent-free process.
To develop a suitable and multifunctional packaging material that is easily processable, we synthesized in-situ growth of octahedral amine-functionalized UiO- 66 on the surface of graphene oxide nanosheets as a filler and used UV curable polymer PEGDA and a solvent-free process to fabricate MMMs. X-Ray diffraction (XRD), Fourier-transform infrared (FTIR), scanning electron microscopy (SEM), dynamic light scattering (DLS), thermogravimetric analysis (TGA), Brunauer- Emmett-Teller (BET), Raman spectroscopy, mechanical properties and single gas permeability were used to characterize fillers and membranes.

關鍵字(中)

★ 紫外線固化工藝
★ 聚乙二醇二丙烯酸酯
★ 修飾金屬有機框架
★ 氧氣阻隔

關鍵字(英)

★ UV curable process
★ PEGDA
★ modified metal organic frameworks
★ oxygen barrier

論文目次

摘要 .......................................................................................................................................... i Abstract ...................................................................................................................................ii Acknowledgement..................................................................................................................iii Table of Contents ...................................................................................................................iv List of Figures ......................................................................................................................viii List of Tables..........................................................................................................................xi
Chapter 1 Introduction ............................................................................................................1
1-1. Background .................................................................................................................1
1-2. Review of Relevant Literature ....................................................................................2 1-2-1. Overview of membrane fabrication methods......................................................2 1-2-2. UV curing process and basic concept .................................................................5 1-2-3. Application of polyethylene glycol diacrylate (PEGDA) ................................... 7 1-2-4. Mixed matrix membranes (MMMs) and its challenge......................................10 1-2-5. Amine-functionalized UiO-66 and Graphene Oxide......................................... 11 1-2-6. Product packaging.............................................................................................13
1-3. Motivation.................................................................................................................14
Chapter 2 Experimental.........................................................................................................16 2-1. Materials and Reagents .............................................................................................16 2-2. Instruments................................................................................................................172-2-1. Amine-functionalized UiO-66 in-situ GO material preparation ....................... 17 2-2-2. Single gas permeation measurement system.....................................................17 2-2-3. Self-assemble UV-curing system for membrane synthesis ............................... 17
2-3. Analysis Instruments and Characterization ............................................................... 18 2-3-1. Fourier-transform infrared spectroscopy (FTIR) ..............................................18 2-3-2. X-ray diffraction (XRD)....................................................................................20 2-3-3. Scanning electron microscopy (SEM)...............................................................20 2-3-4. Energy-dispersive X-ray spectroscopy (EDS) ..................................................22 2-3-5. Dynamic light scattering (DLS) ........................................................................ 23 2-3-6. Thermogravimetric analysis (TGA) .................................................................. 23 2-3-7. Micropore Size and Surface Area Analysis.......................................................24 2-3-8. Mechanical properties ....................................................................................... 25 2-3-9. Raman spectroscopy..........................................................................................26 2-3-10. Single gas separation system...........................................................................27 2-3-11. Coating properties ...........................................................................................29
2-4. Synthesis of Fillers....................................................................................................30 2-4-1. Synthesis of GO ................................................................................................30 2-4-2. Synthesis of UiO-66-NH2 and UiO-66-NH2 in-situ GO ................................... 31
2-5. Preparation of Membranes ........................................................................................ 32 2-5-1. Pristine PEGDA membranes ............................................................................. 32 2-5-2. Mixed matrix membranes..................................................................................32
Chapter 3 Results and Discussion ......................................................................................... 33 3-1. Characterization of GO .............................................................................................33
3-1-1. X-ray diffraction................................................................................................34 3-1-2. FTIR spectrum...................................................................................................35 3-1-3. Raman spectrum................................................................................................36 3-1-4. Morphology.......................................................................................................37 3-1-5. N2 sorption and Surface area.............................................................................39 3-1-6. Thermogravimetric analysis..............................................................................40
3-2. Characterization of UN & UN@GO Powder............................................................41 3-2-1. X-ray diffraction................................................................................................41 3-2-2. FTIR spectrum...................................................................................................42 3-2-3. Raman spectrum................................................................................................43 3-2-4. N2 sorption and surface area.............................................................................44 3-2-5. Pore size distribution.........................................................................................46 3-2-6. Thermogravimetric analysis..............................................................................47 3-2-7. Morphology and Particle size............................................................................48
3-3. Characterization of pristine membranes and MMMs................................................50 3-3-1. X-ray diffraction................................................................................................50 3-3-2. FTIR spectrum...................................................................................................51 3-3-3. Thermogravimetric analysis..............................................................................52 3-3-4. Filler/Polymer interface.....................................................................................55 3-3-5. Filler distributions ............................................................................................. 59 3-3-6. Mechanical Properties.......................................................................................60
3-4. Single Gas Permeation Measurement .......................................................................61 3-5. Coating properties ..................................................................................................... 67
Chapter 4 Conclusions ..........................................................................................................70 Chapter 5 Future Work .......................................................................................................... 71 References ............................................................................................................................. 73

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指導教授

張博凱(Chang, Bor-Kae)

審核日期

2023-7-26

推文