Enantioselective synthesis of (thiolan-2-yl)diphenylmethanol and its application in asymmetric, catalytic sulfur ylide-mediated epoxidation

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題名:	Enantioselective synthesis of (thiolan-2-yl)diphenylmethanol and its application in asymmetric, catalytic sulfur ylide-mediated epoxidation
作者:	吳忻怡;Wu, Hsin-Yi;Chang, Chih-Wei;Chein, Rong-Jie
貢獻者:	總教學中心通識教育中心
關鍵詞:	Benzyl Alcohols - chemical synthesis;Benzyl Alcohols - chemistry;Catalysis;enantiomers;enantioselective synthesis;epoxidation reactions;Epoxy Compounds - chemical synthesis;Epoxy Compounds - chemistry;Lewis bases;Molecular Structure;organic chemistry;Stereoisomerism;Sulfhydryl Compounds - chemical synthesis;Sulfhydryl Compounds - chemistry;sulfur
日期:	2013-06-07
上傳時間:	2026-04-23 12:52:50 (UTC+8)
出版者:	American Chemical Society;United States: American Chemical Society
摘要:	摘要： This work describes an expeditious and efficient preparation of enantiopure (thiolan-2-yl)diphenylmethanol (2) featuring a double nucleophilic substitution and Shi epoxidation as key steps. One of the applications of its benzyl ether derivative to asymmetric sulfur ylide-mediated epoxidation with up to 92% ee (14 examples) was also demonstrated herein. 其他題名： J. Org. Chem 出版者： United States: American Chemical Society 出版日期： 2013-06-07 出處： Journal of organic chemistry, 2013-06, Vol.78 (11), p.5788-5793 資源來源： American Chemical Society Journals 版權： Copyright © 2013 American Chemical Society 識別號： ISSN: 0022-3263 識別號： ISSN: 1520-6904 識別號： EISSN: 1520-6904 識別號： DOI: 10.1021/jo400648f 識別號： PMID: 23638685
顯示於類別:	[通識教育中心] 期刊論文

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