Synthesis, Characterization, and Properties of Organically Templated Lanthanide Oxalatophosphates with a Three-Dimensional Honeycomb Structure: (H(4)APPIP)[Ln(3)(C2O4)(5.5)(H2PO4)(2)] center dot 5H(2)O (Ln = Er-Lu, APPIP 1,4-Bis(3-aminopropyl)piperazine)

Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/29714

Title:	Synthesis, Characterization, and Properties of Organically Templated Lanthanide Oxalatophosphates with a Three-Dimensional Honeycomb Structure: (H(4)APPIP)[Ln(3)(C2O4)(5.5)(H2PO4)(2)] center dot 5H(2)O (Ln = Er-Lu, APPIP 1,4-Bis(3-aminopropyl)piperazine)
Authors:	Wang,CM;Wu,YY;Hou,CH;Chen,CC;Lii,KH
Contributors:	中央大學
Keywords:	CRYSTAL-STRUCTURE;MAGNETIC-PROPERTIES;BIGINELLI REACTION;FRAMEWORK;COMPLEXES;OXALATES;LUMINESCENCE;SPECTROSCOPY
Date:	2009
Issue Date:	2010-06-30 15:00:07 (UTC+8)
Publisher:	化學研究所
Abstract:	Four isostructural organically templated lanthanide oxalatophosphates, (H(4)APPIP)[Ln(3)(C2O4)(5.5)(H2PO4)(2)] center dot 5H(2)O (Ln = Er-Lu and APPIP = 1,4-bis(3-aminopropyl)piperazine), have been synthesized under hydrothermal conditions and characterized by single-crystal and powder X-ray diffraction. Their structures contain LnO(8) trigonal dodecahedra linked by three bis-bidentate oxalates to form layers in the (102) plane, which are connected by dihydrogen phosphate and bis-monodentate oxalate ligands to form a 3D framework. The charge-compensating tetraprotonated 1,4-bis(3-aminopropyl)piperazinium cations and lattice water molecules are located in the 12-membered ring straight channels. They are the first examples of organically templated lanthanide oxalatophosphates. The thermal stability, guest desorption-sorption properties, variable-temperature in situ powder X-ray diffraction, magnetic susceptibility, and photoluminescence spectrum of the Er compound and catalytic activity of the Yb compound for the Biginelli reaction have also been studied.
Relation:	INORGANIC CHEMISTRY
Appears in Collections:	[Graduate Institute of Chemistry] journal & Dissertation

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