Elasticity of tephroite (alpha-Mn(2)SiO(4)) and a comparison of the elastic properties of silicate olivines

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Title:	Elasticity of tephroite (alpha-Mn(2)SiO(4)) and a comparison of the elastic properties of silicate olivines
Authors:	Lin,CC;Chen,CC
Contributors:	地球科學系
Keywords:	SINGLE-CRYSTAL FORSTERITE;X-RAY-DIFFRACTION;HIGH-PRESSURE;BULK MODULUS;BRILLOUIN-SCATTERING;TEMPERATURE;GPA;FAYALITE;COMPRESSION;POLYMORPHS
Date:	2011
Issue Date:	2012-03-27 17:36:47 (UTC+8)
Publisher:	國立中央大學
Abstract:	The elastic constants of pure tephroite (alpha-Mn(2)SiO(4)) have been determined by Brillouin spectroscopy. From measurements, the average aggregate bulk and shear moduli at ambient conditions are 129.8 +/- 0.5 and 53.1 +/- 0.4 GPa, respectively, which also confirm the reality of the unexpected high elastic moduli in tephroite. An analysis based on the present data and those in literature has revealed the relative orders: fayalite > tephroite >= forsterite for bulk modulus and forsterite >> tephroite > fayalite for shear modulus. It also indicates that the propagation velocity of a sound wave inside forsterite will be considerably changed by dissolving a small amount of Mn(2+) and/or Fe(2+) (for shear wave) and Ni(2+) cations (for compressional wave). The causes for the significant difference between forsterite and the 3d silicate olivines and the unexpected elastic behavior in tephroite have been explored by considering the nature of both electron orbitals and MO(6) octahedra.
Relation:	EUROPEAN JOURNAL OF MINERALOGY
Appears in Collections:	[Department of Earth Sciences ] journal & Dissertation

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