Design and Synthesis of a New Type Metal Complex with Dipyridylpyrrole Ligands for Dye-Sensitized Solar Cell Applications

Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/72565

Title:	Design and Synthesis of a New Type Metal Complex with Dipyridylpyrrole Ligands for Dye-Sensitized Solar Cell Applications
Authors:	林家豪;Lin, Chia-Hao
Contributors:	化學學系
Keywords:	DPP
Date:	2016-12-26
Issue Date:	2017-01-23 16:06:25 (UTC+8)
Publisher:	國立中央大學
Abstract:	在染料敏化太陽能電池(DSSC)中，位於吸光層的染料對於效率的影響扮演著非常重要的角色，在本篇研究中使用了以雙吡啶基吡咯結構作為基礎的配位基，我在配位基上藉由修飾延長其共軛長度後，再與鋅 (Zn) 金屬結合，最後加上錨基(Anchoring group)使其成為合適的染料結構，並對所合成出的染料進行其光學性質探討。由於此類配位基錯合物目前為止還未曾使用於染料敏化太陽能電池中做探討，因此這類有別於以往常見的金屬錯合物染料，未來或許會在染料敏化太陽能電池這領域中成為非常具有潛力的一系列染料。;In dye-sensitized solar cells (DSSCs), the dye which located in absorb layer have been considered as a important role for their power conversion efficiency. In this thesis, I used the dipyridylpyrrole as my Ligand, and I modified it for longer conjugation then reacts with Zinc. Finally, I make it a suitable dye structure, and measure the optical properties. So far, there are no any reports about the metal complex of dipyridylpyrrole ligands in DSSCs. In future, the special metal complex may be a very potential dyes in DSSCs.
Appears in Collections:	[Graduate Institute of Chemistry] Electronic Thesis & Dissertation

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