本篇論文分為四個章節。 第一章是綜合論述，包含在現今生活方式下所面臨關於能源儲備的挑戰、關於鋰離子電池的基本原理、傳統商用電池中無機電極材料的限制，以及近期轉向有機電極材料的優勢，並整理與比較目前文獻中含有三嗪類活性材料（共價三嗪骨架、共軛微孔聚合物）應用於陽極材料的表現，以及論文的研究動機。 第二章總結了四種三嗪基活性材料應用於電池陽極的電化學表現及電池效能，其優異的表現強調了分子設計的貢獻。並且進一步以一系列的電化學測試方法探討其電荷儲存的行為及電化學動力學。 第三章簡述了傳統無機陰極材料面臨的挑戰，並探討了兩種經有機分子修飾的還原氧化石墨烯應用於電池陰極的電化學表現，其表現出良好的氧化還原能力以及電化學循環穩定性，並且也進一步由系統性的電化學測試證實其電容量提昇的原因。此電池性能的提昇提供了碳基複合材料於表面修飾的設計策略。 最終第四章總結了本論文內容，並且提出對於電極材料未來發展的期許。 ;This thesis was arranged into four chapters. Chapter 1 is a general introduction, including challenges of current energy storage faced in modern society, fundamentals of lithium-ion batteries, the limitations of conventional inorganic electrode materials, the benefits toward organic materials’ research and summarizes several literatures incorporated triazine unit, covalent triazine frameworks and conjugated microporous polymers as anode materials, as well as the motivation of this thesis. Chapter 2 provides a comprehensive evaluation of triazine-based anode materials, pOMeAni, pOMe2CN, TBPPP33 and diMePyZo, and emphasizes their outstanding performance through the molecular design. A series of electrochemical measurements were carried out to probe their charge storage behavior and electrochemical kinetic studies. Chapter 3 briefly discusses the challenges of traditional inorganic cathode materials and further investigates the battery performance of organic anthraquinone-grafted rGO-based cathode materials, AQ-rGO and APAD-rGO. Both cathode materials exhibit good redox reversibility and cycling stability, which were further confirmed by a set of measurements. The enhanced battery performance offers a valuable surface modification strategy to design new hybrid carbon materials. Chapter 4 summarizes the results of Chapter 2 and 3 and involves the future works and perspective of battery electrode materials.
