dc.description.abstract | Among the many renewable energy, inexhaustible solar energy is the most attended one. Dye-sensitized solar cells possessing the advantages of low-cost, simple process, multi-color, penetration and flexibility, has become one of the key technology to developed.
The photosensitizer is one of important components which affecting the solar cell efficiency in the dye-sensitized solar cells. Compared to the ruthenium metal complexes based sensitizers, the metal-free organic sensitizers shows following advantages:high molar extinction coefficient, easy for structural modification, low cost and lower environmental pollution, etc., and hence, attracted large of studies.
The sensitizers DD101 representing the D-π-A configuration, in which 2-phenylthiophene as the π-bridge of the dye, were designed and synthesized. Next, we made modification to design the series of sensitizers DD104, DD113 and DD114 to represent the 2D-π-2A configuration, in which 2,2’-(1,3-phenylene)bis-thiophene were incorporated in the π-bridge of the dye. Then, further investigation of various of donors which affect the power conversion efficiency of 2,2’-(1,3-phenylene)bis-thiophene sensitizers are studied to. | en_US |