DC 欄位 值 語言 DC.contributor 化學學系 zh_TW DC.creator 王劭群 zh_TW DC.creator Shao-Chun Wang en_US dc.date.accessioned 2014-8-14T07:39:07Z dc.date.available 2014-8-14T07:39:07Z dc.date.issued 2014 dc.identifier.uri http://ir.lib.ncu.edu.tw:444/thesis/view_etd.asp?URN=101223024 dc.contributor.department 化學學系 zh_TW DC.description 國立中央大學 zh_TW DC.description National Central University en_US dc.description.abstract 類沸石咪唑骨架材料是屬於金屬有機骨架材料的範疇，其主要是利用咪唑或是咪唑衍生 物(Im)當作有機配位體與鋅、鈷等過渡金屬(M)鍵結所形成的聚合物，結構中Im-M-Im的 鍵結角度約為145度，與天然沸石中Si-O-Si的鍵結角度大約相同，故被稱之為類沸石咪 唑骨架材料，目前主要有儲存氣體、分離混和氣體、非均相催化和藥物載體的應用。本 論文所介紹的類沸石咪唑骨架材料-90(Zeolitic Imidazolate Framework-90；ZIF-90) 已有報導指出此材料易於官能基化的特點，並具有極為優異的水熱穩定性。然而，目前 合成ZIF-90之方法大多需使用有機溶劑(如DMF)，但若大量製造ZIF-90時，所產生的廢 液將對於環境造成負擔。為了符合綠色化學之製程，此研究中，我們提供了一種於水相 系統中製備ZIF-90之方法，能夠製造出粒徑大小一致且尺寸具有均一性的ZIF-90。 zh_TW dc.description.abstract In zeolitic imidazolate frameworks (ZIFs), a subclass of metal–organic frameworks (MOFs), metal ions such as Zn2+ and Co2+ are linked through the nitrogen atoms of the deprotonated imidazolate to form neutral frameworks and provide a tunable crystalline structure and porosity and a high internal surface area. Additionally, the M–Im–M angle is similar to that of the Si–O–Si angle (145o) preferred in zeolites. This fact has led to the synthesis of a large number of ZIFs with zeolite-type tetrahedral topologies. Therefore, ZIFs have recently attracted considerable attention for applications in gas storage, separation of small molecules, heterogeneous catalysis, sensors and drug delivery. Zeolitic Imidazolate Framework-90 (ZIF-90), the main character of the thesis, was reported to have high thermal and solvent stability. However, most of the strategies reported so far on the synthesis of ZIF-90 have involved the use of solvents, such as dimethyl formamide (DMF), methanol, or other organic solvents which are also expensive, in addition to their environmental concerns, such as toxicity, high-pollution, and waste treatment issues. Herein, we report for the first time, a rapid and eco-friendly strategy for the synthesis of ZIF-90 under aqueous conditions, and thus, ZIF-90 having uniform particle sizes can be produced. en_US DC.subject 微孔洞材料 zh_TW DC.subject 類沸石咪唑骨架材料 zh_TW DC.subject 固定化酵素 zh_TW DC.subject 金屬有機骨架材料 zh_TW DC.subject 環保 zh_TW DC.subject Microporous material en_US DC.subject Zeolitic imidazolate framework en_US DC.subject Immobolized enzyme en_US DC.subject Metal-organic framework en_US DC.subject Environmental friendly en_US DC.title 以水相系統合成類沸石咪唑骨架材料(ZIF-90)及其在生物酵素催化上的應用 zh_TW dc.language.iso zh-TW zh-TW DC.title Water-Based Synthesis of Zeolitic Imidazolate Framework-90 (ZIF-90) with a Controllable Particle Size and its Application in Biocatalysis en_US DC.type 博碩士論文 zh_TW DC.type thesis en_US DC.publisher National Central University en_US