博碩士論文 110324077 完整後設資料紀錄

DC 欄位 語言
DC.contributor化學工程與材料工程學系zh_TW
DC.creator賴弘宇zh_TW
DC.creatorHONG-YU LAIen_US
dc.date.accessioned2023-7-26T07:39:07Z
dc.date.available2023-7-26T07:39:07Z
dc.date.issued2023
dc.identifier.urihttp://ir.lib.ncu.edu.tw:444/thesis/view_etd.asp?URN=110324077
dc.contributor.department化學工程與材料工程學系zh_TW
DC.description國立中央大學zh_TW
DC.descriptionNational Central Universityen_US
dc.description.abstract包裝在許多領域扮演著重要的角色,例如食品、藥品、電子產品等。 此 外,氧氣阻隔性能有時是包裝材料最關鍵的討論因素。隨著技術的進步和行業 的進步,我們需要開發智能包裝以應用於不同的領域。 混合基質薄膜 (MMMs) 常用於分離混合氣體。 此外,混合基質薄膜通常是 通過澆鑄方法合成的,即將前體溶液倒在板上,然後通過蒸發去除溶劑。 這項 研究的重點是另一種通過紫外線固化製造膜的方法,與熱固化聚合物塗層相 比,它具有明顯的優勢。 除了固化時間快之外,紫外線固化還涉及較低的資本 投資和運營成本,並且是一種無溶劑工藝。 為了開發一種易於加工的合適的多功能包裝材料,我們在氧化石墨烯上原 位生長了正八面體 的 UiO-66-NH2, 以此作為填料。並使用快速的 UV 固化聚 合物聚乙二醇二丙烯酸酯和無溶劑工藝來製造混合基質薄膜。 並利用 X 射線衍 射儀 (XRD)、傅里葉轉換紅外光譜 (FTIR)、超高解析冷場發射掃描式電子顯微 鏡 (SEM)、動態光散射 (DLS)、熱重分析 (TGA)、Brunauer-Emmett-Teller (BET)、拉曼光譜、機械性能、單一氣體滲透實驗用於表徵填料和膜。zh_TW
dc.description.abstractPackaging plays an important role in our daily life in many fields, such as food, medicine, and electronic products. Besides, oxygen barrier performance is sometimes the most critical discussion factor for packaging materials. With advances in technology and industry progress, we need to develop intelligent packaging to apply to different fields. Mixed matrix membranes (MMMs) are popular for separating mixed gases. Moreover, MMMs are synthesized using a casting method, wherein the precursor solution is poured onto a plate, and then the solvent is removed through evaporation. This research focuses on another way to fabricate membranes via UV curing, which provides distinct advantages compared to thermally cured polymer coatings. In addition to the fast curing time, UV curing also involves lower capital investment and operating costs and is a solvent-free process. To develop a suitable and multifunctional packaging material that is easily processable, we synthesized in-situ growth of octahedral amine-functionalized UiO- 66 on the surface of graphene oxide nanosheets as a filler and used UV curable polymer PEGDA and a solvent-free process to fabricate MMMs. X-Ray diffraction (XRD), Fourier-transform infrared (FTIR), scanning electron microscopy (SEM), dynamic light scattering (DLS), thermogravimetric analysis (TGA), Brunauer- Emmett-Teller (BET), Raman spectroscopy, mechanical properties and single gas permeability were used to characterize fillers and membranes.en_US
DC.subject紫外線固化工藝zh_TW
DC.subject聚乙二醇二丙烯酸酯zh_TW
DC.subject修飾金屬有機框架zh_TW
DC.subject氧氣阻隔zh_TW
DC.subjectUV curable processen_US
DC.subjectPEGDAen_US
DC.subjectmodified metal organic frameworksen_US
DC.subjectoxygen barrieren_US
DC.title紫外線固化含改質金屬有機框架材料混合基質薄膜應用於產品包裝zh_TW
dc.language.isozh-TWzh-TW
DC.titleUV Curing Mixed Matrix Membrane Containing Modified Metal-Organic Frameworks for Product Packagingen_US
DC.type博碩士論文zh_TW
DC.typethesisen_US
DC.publisherNational Central Universityen_US

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