博碩士論文 87321017 完整後設資料紀錄

DC 欄位 語言
DC.contributor化學工程與材料工程學系zh_TW
DC.creator陳慶松zh_TW
DC.creatorChin-Sung Chenen_US
dc.date.accessioned2000-7-1T07:39:07Z
dc.date.available2000-7-1T07:39:07Z
dc.date.issued2000
dc.identifier.urihttp://ir.lib.ncu.edu.tw:444/thesis/view_etd.asp?URN=87321017
dc.contributor.department化學工程與材料工程學系zh_TW
DC.description國立中央大學zh_TW
DC.descriptionNational Central Universityen_US
dc.description.abstract本研究主要針對嵌印高分子及離子交換樹脂在近等電點時的吸附機制進行探討,實驗上主要是利用恆溫滴定微卡計(Isothermal Titration Calorimetry,ITC)量測吸附熱及配合等溫吸附線的建立,期望從熱力學的角度來研究分析。 在嵌印高分子及離子交換樹脂在近等電點時的吸附機制研究方面,我們分別提出了模板分子2,4-D與嵌印高分子及控制組高分子的可能鍵結程序,並說明各鍵結程序對於整個系統的焓△Hads與火商 △Sads 的影響及zh_TW
dc.description.abstractThe aim of the research is to provide the insight of the binding mechanism of imprinting polymer and ion-exchange resin near isoelectric point by isotherm curve analysis and adsorption enthalpy measurement by microcalorimetry. We suggested a possible binding processes of 2,4-dichlorophoxyacetic acid (2,4-D) adsorbing on imprinting and control polymers and divided the process into four subprocesses; (a) dehydration process of imprinting polymer; (b) dehydration process of 2,4-D; (c) binding process of 2,4-D adsorbing on imprinting polymer and (d) rearragement process of water molecules after 2,4-D adsorbing on imprinting polymer. The thermodynamic information accompany the suggested process were also discussed. The data measured using isothermal titration calorimetry (ITC) for both imprinting and control polymers reveals the values of adsorption enthalpy (en_US
DC.subject乳球蛋白zh_TW
DC.subject嵌印高分子zh_TW
DC.subject吸附機制zh_TW
DC.subjectbata-lactoglibulinen_US
DC.subjectimprinting polymeren_US
DC.subjectadsorptien_US
DC.title微卡計在固液吸附機制的研究-嵌印高分子及離子交換樹脂在近等電點時的吸附機制zh_TW
dc.language.isozh-TWzh-TW
DC.titleMicrocalorimetric studies of adsorption mechanism between solid and liquid-adsorption mechanism studies of imprinting polymer and ion-exchange resin near isoelectric pointen_US
DC.type博碩士論文zh_TW
DC.typethesisen_US
DC.publisherNational Central Universityen_US

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